Electrical Behaviour and Spherulites Morphology of HDPE/PP Polyblends with HDPE as Base Material
- 1 Chemical Engineering Department, Indira Gandhi Institute of Technology, Sarang, India
- 2 Chemical Engineering Department, Indira Gandhi Institute of Technology, Sarang, India
- 3 Chemical Engineering Department, Indira Gandhi Institute of Technology, Sarang, India
- 4 Chemical Engineering Department, National Institute of Technology, Trichy, India
- 5 Chemical Engineering Department, Jadavpur University, Kolkata, India
Abstract
Polymer composites of virgin high density poly ethylene (HDPE) and virgin polypropylene (PP) are prepared. PP of weight% of 20, 30 and 50 are reinforced to HDPE in the form of pellets. They are converted into raw polymer sheets using a two roll milling machine. The prepared raw sheets have undergone compression moulding to fabricate polymer sheets to study electrical properties like dielectric strength, surface resistivity and volume resistivity at atmospheric temperature and pressure. Result shows dielectric strength and volume resistivity decreases with addition of PP to HDPE, whereas surface resistivity increases. Crystal growth rate is observed using a cross polarised microscope (PLM). The microscopy results reveal, the PP crystallizes faster than HDPE and the growth rate declines for the polyblend; showing non-uniform and hazy spherulitic structure.
- Teroda, M. and Ohaba, Y. (1983) Energy Transfer Mechanism and Amplified Spontaneous Emission Characteristics of Dye Mixture Solutions. Journal of Applied Physics, 22, 1392-1396. https://doi.org/10.1143/JJAP.22.1392
- Gulrez, S.K.H., Ali Mohsin, M.E., Shaikh, H., Anis, A., Pulose, A.M., Yadav, M.K., Qua, E.H.P. and Al-Zahrani, S.M. (2014) A Review on Electrically Conductive Poly-propylene and Polyethylene. Polymer Composites, 35, 900-914. https://doi.org/10.1002/pc.22734
- Walker, B.M. and Rader, C.P. (1979) Handbook of Thermoplastic Elastomers. Van Nostrand Reinhold, New York.
- Malik, T.M. and Prudhornme, R.E. (1984) Dielectric Properties of Poly(α-Methyl α-n-Propyl-β-Propiolactone)/Poly(Vinyl Chloride) Blends. Polymer Engineering & Science, 24, 144-152. https://doi.org/10.1002/pen.760240212
- Pathrnanathan, K., Cavaille, J.Y. and Johari, G.P. (1988) Dielectric Relaxations of Microstructurally Different Latex Polymer Blends of Poly(Butyl Acrylate) and Poly(Vinyl Acetate). Polymer, 29, 311-319. https://doi.org/10.1016/0032-3861(88)90339-4
- Maistros, G.M., Block, H., Bucknall, C.B. and Patridge, I.K. (1992) Dielectric Monitoring of Phase Separation during Cure of Blends of Epoxy Resin with Carboxyl-Terminated Poly(Butadiene-Co-Acrylonitrile). Polymer, 33, 4470-4478. https://doi.org/10.1016/0032-3861(92)90402-I
- Pillai, P.K.C., Narula, G.R. and Tripathy, A.K. (1984) Dielectric Properties of Polypropyl-ene/Polycarbonate Polyblends. Polymer Journal, 16, 575-578.
- Radhakrishnan, S. and Saini, D.R. (1994) Structure and Dielectric Properties of Poly(Vinyl Chloride) Thermoplastic Elastomer Blends. Journal of Applied Polymer Science, 52, 1577-1586. https://doi.org/10.1002/app.1994.070521106
- Gustafsson, A., Salot, R. and Gedde, U.W. (1993) Electrical Degradation of Blends and Laminar Composites of Polyethylene and Polystyrene. Polymer Composites, 14, 421-429. https://doi.org/10.1002/pc.750140509
- Mansour, A.A., Sabagh, S.E.L. and Yehia, A.A. (1994) Dielectric Investigation of SBR-NBR and CR-NBR Blends. Journal of Elastomers & Plastics, 26, 367. https://doi.org/10.1177/009524439402600406
- Elashmawi, I.S., Hakeem, N.A. and Abdelrazek, E.M. (2008) Spectroscopic and Thermal Studies of PS/PVAc Blends. Physica B: Condensed Matter, 403, 3547-3552. https://doi.org/10.1016/j.physb.2008.05.024
- Ramesh, S., Yahaya, A.H. and Arof, A.K. (2002) Miscibility Studies of PVC Blends (PVC/PMMA and PVC/PEO) Based Polymer Electrolytes. Solid State Ionics, 148, 483-486. https://doi.org/10.1016/S0167-2738(02)00091-7