Effect of Ultra-Turrax on Nanocellulose Produced by Acid Hydrolysis and Modified by Nano ZnO by Sol-Gel Method — Oak Academic Publishing
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Effect of Ultra-Turrax on Nanocellulose Produced by Acid Hydrolysis and Modified by Nano ZnO by Sol-Gel Method
Instituto de Macromoléculas Professora Eloisa Mano, Universidade Federal do Rio de Janeiro, Bl J do Centro de Tecnologia, Ilh do Fundao, Rio de Janeiro, RJ, Brasil
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Instituto SENAI de Inovacao em Biossintéticos e Fibras, Universidade Federal do Rio de Janeiro, Rio de Janeiro, Brasil
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Instituto de Macromoléculas Professora Eloisa Mano, Universidade Federal do Rio de Janeiro, Bl J do Centro de Tecnologia, Ilh do Fundao, Rio de Janeiro, RJ, Brasil
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Instituto de Biofísica Carlos Chagas, Universidade Federal do Rio de Janeiro, Rio de Janeiro, Brasil
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Divisao de Metrologia de Materiais, Instituto Nacional de Metrologia, Qualidade e Tecnologia (INMETRO), Duque de Caxias, Brasil
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Divisao de Metrologia de Materiais, Instituto Nacional de Metrologia, Qualidade e Tecnologia (INMETRO), Duque de Caxias, Brasil
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Instituto de Macromoléculas Professora Eloisa Mano, Universidade Federal do Rio de Janeiro, Bl J do Centro de Tecnologia, Ilh do Fundao, Rio de Janeiro, RJ, Brasil
1 Instituto de Macromoléculas Professora Eloisa Mano, Universidade Federal do Rio de Janeiro, Bl J do Centro de Tecnologia, Ilh do Fundao, Rio de Janeiro, RJ, Brasil
2 Instituto SENAI de Inovacao em Biossintéticos e Fibras, Universidade Federal do Rio de Janeiro, Rio de Janeiro, Brasil
3 Instituto de Macromoléculas Professora Eloisa Mano, Universidade Federal do Rio de Janeiro, Bl J do Centro de Tecnologia, Ilh do Fundao, Rio de Janeiro, RJ, Brasil
4 Instituto de Biofísica Carlos Chagas, Universidade Federal do Rio de Janeiro, Rio de Janeiro, Brasil
5 Divisao de Metrologia de Materiais, Instituto Nacional de Metrologia, Qualidade e Tecnologia (INMETRO), Duque de Caxias, Brasil
6 Divisao de Metrologia de Materiais, Instituto Nacional de Metrologia, Qualidade e Tecnologia (INMETRO), Duque de Caxias, Brasil
7 Instituto de Macromoléculas Professora Eloisa Mano, Universidade Federal do Rio de Janeiro, Bl J do Centro de Tecnologia, Ilh do Fundao, Rio de Janeiro, RJ, Brasil
Cellulose nanocrystals (NCC) and cellulose nanofibrils (CNF) were obtained by a single step process, with synergy between 64% sulfuric acid hydrolysis and high shear from ultra-turrax stirring, which is an advantageous process for disintegrating cellulose microcrystalline and also may improve the hydrolysis process. The surface modification on the cellulose was performed by the sol-gel process, in which the sulfate groups from hydrolysis were replaced by nanoparticles of zinc oxide, which led to the increase of up to 54 ° C Tonset, according to thermogravimetric analysis (TGA) results. The morphology and crystallinity degree were characterized by Helium Ion Microscopy (HIM), atomic force microscopy (AFM) and X-ray diffraction. In addition, the ZnO band was observed in Fourier transform infrared spectroscopy, furthermore, the change in the zeta potential confirmed the cellulose modification. The changes in the values of proton spin-spin relaxation time for the systems showing the confined hydrogen in the rigid domains, confirmed the results observed with the aforementioned techniques, for both cellulose after hydrolysis and ZnO modified cellulose, suggesting that ZnO disrupted crystal formation in cellulose.
Kargarzadeh, H., Mariano, M., Huang, J., Lin, N., Ahmad, I., Dufresne, A. and Thomas, S. (2017) Recent Developments on Nanocellulose Reinforced Polymer Nanocomposites: A Review. Polymer, 132, 368-393. https://doi.org/10.1016/j.polymer.2017.09.043
Wang, N., Ding, E. and Cheng, R. (2007) Thermal Degradation Behaviors of Spherical Cellulose Nanocrystals with Sulfate Groups. Polymer, 48, 3486-3493. https://doi.org/10.1016/j.polymer.2007.03.062
Bondeson, D., Mathew, A. and Oksman, K. (2006) Optimization of the Isolation of Nanocrystals from Microcrystalline Cellulose by Acid Hydrolysis. Cellulose, 13, 171. https://doi.org/10.1007/s10570-006-9061-4
Li, B., Xu, W., Kronlund, D., Maattanen, A., Liu, J., Smatt, J.-H., Peltonen, J., Willfor, S., Mu, X. and Xu, C. (2015) Cellulose Nanocrystals Prepared via Formic Acid Hydrolysis Followed by TEMPO-Mediated Oxidation. Carbohydrate Polymers, 133, 605-612. https://doi.org/10.1016/j.carbpol.2015.07.033
Melo, A.R.A., da Silva, E.O., Menezes, L.R. and Tavares, M.I.B. (2018) The Effect of Modified Cellulose Particles on Morphology and Properties Ethylene Vinyl Acetate Copolymer. Polymer Testing, 68, 333-339. https://doi.org/10.1016/j.polymertesting.2018.04.012
Camarero Espinosa, S., Kuhnt, T., Foster, E.J. and Weder, C. (2013) Isolation of Thermally Stable Cellulose Nanocrystals by Phosphoric Acid Hydrolysis. Biomacromolecules, 14, 1223-1230. https://doi.org/10.1021/bm400219u
Chen, L., Zhu, J., Baez, C., Kitin, P. and Elder, T. (2016) Highly Thermal-Stable and Functional Cellulose Nanocrystals and Nanofibrils Produced Using Fully Recyclable Organic Acids. Green Chemistry, 18, 3835-3843. https://doi.org/10.1039/C6GC00687F
Xu, W.-J., Zhai, J.-W., Cui, Q., Liu, J.-Z., Luo, M., Fu, Y.-J. and Zu, Y.-G. (2016) Ultra-Turrax Based Ultrasound-Assisted Extraction of Five Organic Acids from Honeysuckle (Lonicera japonica Thunb.) and Optimization of Extraction Process. Separation and Purification Technology, 166, 73-82. https://doi.org/10.1016/j.seppur.2016.04.003
Liu, Y., Wang, H., Yu, G., Yu, Q., Li, B. and Mu, X. (2014) A Novel Approach for the Preparation of Nanocrystalline Cellulose by Using Phosphotungstic Acid. Carbohydrate Polymers, 110, 415-422. https://doi.org/10.1016/j.carbpol.2014.04.040
Lu, Q., Cai, Z., Lin, F., Tang, L., Wang, S. and Huang, B. (2016) Extraction of Cellulose Nanocrystals with a High Yield of 88% by Simultaneous Mechanochemical Activation and Phosphotungstic Acid Hydrolysis. ACS Sustainable Chemistry & Engineering, 4, 2165-2172. https://doi.org/10.1021/acssuschemeng.5b01620
Boujemaoui, A., Mongkhontreerat, S., Malmstrom, E. and Carlmark, A. (2015) Preparation and Characterization of Functionalized Cellulose Nanocrystals. Carbohydrate Polymers, 115, 457-464. https://doi.org/10.1016/j.carbpol.2014.08.110
Jia, C., Chen, L., Shao, Z., Agarwal, U.P., Hu, L. and Zhu, J.Y. (2017) Using a Fully Recyclable Dicarboxylic Acid for Producing Dispersible and Thermally Stable Cellulose Nanomaterials from Different Cellulosic Sources. Cellulose, 24, 2483-2498. https://doi.org/10.1007/s10570-017-1277-y
Li, D., Henschen, J. and Ek, M. (2017) Esterification and Hydrolysis of Cellulose Using Oxalic Acid Dihydrate in a Solvent-Free Reaction Suitable for Preparation of Surface-Functionalised Cellulose Nanocrystals with High Yield. Green Chemistry, 19, 5564-5567. https://doi.org/10.1039/C7GC02489D
Tang, L., Huang, B., Lu, Q., Wang, S., Ou, W., Lin, W. and Chen, X. (2013) Ultrasonication-Assisted Manufacture of Cellulose Nanocrystals Esterified with Acetic Acid. Bioresource Technology, 127, 100-105. https://doi.org/10.1016/j.biortech.2012.09.133
Kargarzadeh, H., Ahmad, I., Abdullah, I., Dufresne, A., Zainudin, S.Y. and Sheltami, R.M. (2012) Effects of Hydrolysis Conditions on the Morphology, Crystallinity and Thermal Stability of Cellulose Nanocrystals Extracted from Kenaf Bast Fibers. Cellulose, 19, 855-866. https://doi.org/10.1007/s10570-012-9684-6
Wang, Q.Q., Zhao, X. and Zhu, J.Y. (2014) Kinetics of Strong Acid Hydrolysis of a Bleached Kraft Pulp for Producing Cellulose Nanocrystals (CNCs). Industrial & Engineering Chemistry Research, 53, 11007-11014. https://doi.org/10.1021/ie501672m
Hamad, W.Y. and Hu, T.Q. (2010) Structure-Process-Yield Interrelations in Nanocrystalline Cellulose Extraction. The Canadian Journal of Chemical Engineering, 88, 392-402. https://doi.org/10.1002/cjce.20298
Wang, Q.Q., Zhu, J.Y., Reiner, R.S., Verrill, S.P., Baxa, U. and McNeil, S.E. (2012) Cellulose Loss in Cellulose Nanocrystal (CNC) Production: Recovery and Characterization of Cellulosic Solid Residues (CSR) and CNCApproaching Zero. Cellulose, 19, 2033-2047. https://doi.org/10.1007/s10570-012-9765-6
Aguayo, M., Fernández Pérez, A., Reyes, G., Oviedo, C., Gacitúa, W., Gonzalez, R. and Uyarte, O. (2018) Isolation and Characterization of Cellulose Nanocrystals from Rejected Fibers Originated in the Kraft Pulping Process. Polymers, 10, 1145. https://doi.org/10.3390/polym10101145
Chen, L., Wang, Q., Hirth, K., Baez, C., Agarwal, U.P. and Zhu, J. (2015) Tailoring the Yield and Characteristics of Wood Cellulose Nanocrystals (CNC) Using Concentrated Acid Hydrolysis. Cellulose, 22, 1753-1762. https://doi.org/10.1007/s10570-015-0615-1
Grishkewich, N., Mohammed, N., Tang, J. and Tam, K.C. (2017) Recent Advances in the Application of Cellulose Nanocrystals. Current Opinion in Colloid & Interface Science, 29, 32-45. https://doi.org/10.1016/j.cocis.2017.01.005
Arputharaj, A., Nadanathangam, V. and Shukla, S.R. (2017) A Simple and Efficient Protocol to Develop Durable Multifunctional Property to Cellulosic Materials Using in Situ Generated Nano-ZnO. Cellulose, 24, 3399-3410. https://doi.org/10.1007/s10570-017-1335-5
Jia, M., Zhang, X., Weng, J., Zhang, J. and Zhang, M. (2019) Protective Coating of Paper Works: ZnO/Cellulose Nanocrystal Composites and Analytical Characterization. Journal of Cultural Heritage, 38, 64-74. https://doi.org/10.1016/j.culher.2019.02.006
Khosravian, S., Montazer, M., Malek, R.M. and Harifi, T. (2015) In Situ Synthesis of Nano ZnO on Starch Sized Cotton Introducing Nano Photo Active Fabric Optimized with Response Surface Methodology. Carbohydrate Polymers, 132, 126-133. https://doi.org/10.1016/j.carbpol.2015.05.085
Azizi, S., Ahmad, M., Mahdavi, M. and Abdolmohammadi, S. (2013) Preparation, Characterization and Antimicrobial Activities of ZnO Nanoparticles/Cellulose Nanocrystal Nanocomposites. BioResources, 8, 1841-1851. https://doi.org/10.15376/biores.8.2.1841-1851
Azizi, S., Ahmad, M.B., Ibrahim, N.A., Hussein, M.Z. and Namvar, F. (2014) Cellulose Nanocrystals/ZnO as a Bifunctional Reinforcing Nanocomposite for Poly (Vinyl Alcohol)/Chitosan Blend Films: Fabrication, Characterization and Properties. International Journal of Molecular Sciences, 15, 11040-11053. https://doi.org/10.3390/ijms150611040
Anvzlovar, A., Orel, Z.C., Kogej, K. and Zigon, M. (2012) Polyol-Mediated Synthesis of Zinc Oxide Nanorods and Nanocomposites with Poly (Methyl Methacrylate). Journal of Nanomaterials, 2012, Article ID: 760872.
Jia, W., Dang, S., Liu, H., Zhang, Z., Yu, C., Liu, X. and Xu, B. (2012) Evidence of the Formation Mechanism of ZnO in Aqueous Solution. Materials Letters, 82, 99-101. https://doi.org/10.1016/j.matlet.2012.05.013
Li, X., Zhang, X., Li, L., Huang, L., Zhang, W. and Ye, J. (2016) Preparation of Nano-ZnO/Regenerated Cellulose Composite Particles via Co-Gelation and Low-Temperature Hydrothermal Synthesis. Materials Letters, 175, 122-125. https://doi.org/10.1016/j.matlet.2016.04.012
Znaidi, L. (2010) Sol-Gel-Deposited ZnO Thin Films: A Review. Materials Science and Engineering: B, 174, 18-30. https://doi.org/10.1016/j.mseb.2010.07.001
Eyholzer, C., Bordeanu, N., Lopez-Suevos, F., Rentsch, D., Zimmermann, T. and Oksman, K. (2010) Preparation and Characterization of Water-Redispersible Nanofibrillated Cellulose in Powder Form. Cellulose, 17, 19-30. https://doi.org/10.1007/s10570-009-9372-3
Jin, E., Guo, J., Yang, F., Zhu, Y., Song, J., Jin, Y. and Rojas, O. J. (2016) On the Polymorphic and Morphological Changes of Cellulose Nanocrystals (CNC-I) Upon Mercerization and Conversion to CNC-II. Carbohydrate Polymers, 143, 327-335. https://doi.org/10.1016/j.carbpol.2016.01.048
Khoshkava, V. and Kamal, M. (2014) Effect of Drying Conditions on Cellulose Nanocrystal (CNC) Agglomerate Porosity and Dispersibility in Polymer Nanocomposites. Powder Technology, 261, 288-298. https://doi.org/10.1016/j.powtec.2014.04.016
Sèbe, G., Ham-Pichavant, F., Ibarboure, E., Koffi, A.L.C. and Tingaut, P. (2012) Supramolecular Structure Characterization of Cellulose II Nanowhiskers Produced by Acid Hydrolysis of Cellulose I Substrates. BioMacromolecules, 13, 570-578. https://doi.org/10.1021/bm201777j
Jayachandiran, J., Vajravijayan, S., Nandhagopal, N., Gunasekaran, K. and Nedumaran, D. (2019) Fabrication and Characterization of ZnO Incorporated Cellulose Microfiber Film: Structural, Morphological and Functional Investigations. Journal of Materials Science: Materials in Electronics, 30, 6037-6049. https://doi.org/10.1007/s10854-019-00904-1
Singh, A., Viswanath, V. and Janu, V. (2009) Synthesis, Effect of Capping Agents, Structural, Optical and Photoluminescence Properties of ZnO Nanoparticles. Journal of Luminescence, 129, 874-878. https://doi.org/10.1016/j.jlumin.2009.03.027
Nam, S., French, A.D., Condon, B.D. and Concha, M. (2016) Segal Crystallinity Index Revisited by the Simulation of X-Ray Diffraction Patterns of Cotton Cellulose Iβ and Cellulose II. Carbohydrate Polymers, 135, 1-9. https://doi.org/10.1016/j.carbpol.2015.08.035
Ramírez, J.A.á., Suriano, C.J., Cerrutti, P. and Foresti, M.L. (2014) Surface Esterification of Cellulose Nanofibers by a Simple Organocatalytic Methodology. Carbohydrate Polymers, 114, 416-423. https://doi.org/10.1016/j.carbpol.2014.08.020
Giraldi, T.R., Santos, G.V., Mendonca, V.R., Ribeiro, C. and Weber, I.T. (2011) Annealing Effects on the Photocatalytic Activity of ZnO Nanoparticles. Journal of Nanoscience and Nanotechnology, 11, 3635-3640. https://doi.org/10.1166/jnn.2011.3801
Grunin, L.Y., Grunin, Y.B., Nikolskaya, E.A., Sheveleva, N.N. and Nikolaev, I.A. (2017) An NMR Relaxation and Spin Diffusion Study of Cellulose Structure during Water Adsorption. Biophysics (Russian Federation), 62, 198-206. https://doi.org/10.1134/S0006350917020087
Mackay, A.L., Tepfer, M., Taylor, I.E.P. and Volke, F. (1985) Proton Nuclear Magnetic Resonance Moment and Relaxation Study of Cellulose Morphology. Macromolecules, 18, 1124-1129. https://doi.org/10.1021/ma00148a013
Papon, A., Saalwachter, K., Schaler, K., Guy, L., Lequeux, F. and Montes, H. (2011) Low-Field NMR Investigations of Nanocomposites: Polymer Dynamics and Network Effects. Macromolecules, 44, 913-922. https://doi.org/10.1021/ma102486x