Research ArticleOpen AccessGoogle Scholar indexed
Precise Synthesis of Acrylate Copolymer via RAFT Polymerization and Its Application
Transfar Zhilian Co., Ltd., Hangzhou, China
Transfar Zhilian Co., Ltd., Hangzhou, China
Transfar Zhilian Co., Ltd., Hangzhou, China
Transfar Zhilian Co., Ltd., Hangzhou, China
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, China
Transfar Zhilian Co., Ltd., Hangzhou, China
Transfar Zhilian Co., Ltd., Hangzhou, China
- 1 Transfar Zhilian Co., Ltd., Hangzhou, China
- 2 Transfar Zhilian Co., Ltd., Hangzhou, China
- 3 Transfar Zhilian Co., Ltd., Hangzhou, China
- 4 Transfar Zhilian Co., Ltd., Hangzhou, China
- 5 College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, China
- 6 Transfar Zhilian Co., Ltd., Hangzhou, China
- 7 Transfar Zhilian Co., Ltd., Hangzhou, China
Journal of Materials Science and Chemical Engineering·Volume 09 (2021)·Pages 59–67·Published 29 June 2021·DOI10.4236/msce.2021.96005
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Abstract
A series of different sequence structure containing stearyl acrylate (SA) and hydroxyethyl acrylate (HEA) copolymer were synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization. The crystallization property of PHEA- b -PSA, PHEA- b -PSA- b -PHEA, PSA- b -PHEA- b -PSA, PHEA- co -PSA, and PHEA- grad-b -PSA were characterized by Differential Scanning Calorimetry (DSC). The condensed structure of different sequence copolymers were investigated using small-angle X-ray scattering (SAXS). A series of copolymers with different sequence structure were coated on the surface of polyester fabric, which can be found that PHEA-b-PSA-b-PHEA block copolymer has good water repellency.
KeywordsRAFT PolymerizationDifferent Sequence StructureCrystallization Prop-ertyWater Repellency
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