Overview of Precious Metal Content Analysis Methods in Automotive Catalytic Converter
- 1 Department of National Internal Combustion Engine Industry Measuring and Testing Center, Weifang, China
- 2 Department of Weichai Power Co. Ltd., Weifang, China
- 3 Department of National Internal Combustion Engine Industry Measuring and Testing Center, Weifang, China
- 4 Department of National Internal Combustion Engine Industry Measuring and Testing Center, Weifang, China
- 5 Department of National Internal Combustion Engine Industry Measuring and Testing Center, Weifang, China
- 6 Department of National Internal Combustion Engine Industry Measuring and Testing Center, Weifang, China
- 7 Department of National Internal Combustion Engine Industry Measuring and Testing Center, Weifang, China
Abstract
With the increasing awareness of environmental protection, people’s concern of pollution issues arising. Vehicles, as the most important means of transportation, its exhaust emission has received considerable attention. The catalytic converter is able to purify harmful substances in exhaust gas. The absolute content of precious metals in the catalytic converter dominates the exhaust gas purification effect. Accurate detection of precious metal content is of great significance for controlling the cost of catalysts, ensuring catalytic performance and recovering precious metals from spent catalysts. We herein summarized several instruments for precious metals content exploration, such as X-ray fluorescence spectrometer (XRF), atomic absorption spectrometer (AAS), inductively coupled plasma emission spectrometer (ICP) and spectrophotometer. In this thesis, the feasibility of using various devices for characterizing precious metal content in catalytic converters is analyzed and their strengths or weaknesses are elaborated.
- Zand, A.D., Bidhendi, G.N., Alireza, M.T. and Pezeshk, H. (2007) The Influence of Deposit Control Additives on Exhaust CO and HC Emissions from Gasoline Engines. Transportation Research Part D: Transport and Environment, 12, 189-194. https://doi.org/10.1016/j.trd.2007.01.010
- Su, Q., Xie, L., Li Y. and Qiao, X. (2014) Detailed Kinetic Modelling of Automotive Exhaust NOx Reduction over Rhodium Catalyst. The Canadian Journal of Chemical Engineering, 92, 1579-1586. https://doi.org/10.1002/cjce.22021
- Bharathiraja, M., Venkatachalam, R. and Senthilmurugan, V. (2019) Performance, Emission, Energy and Exergy Analyses of Gasoline Fumigated DI Diesel Engine. Journal of Thermal Analysis and Calorimetry, 136, 281-293. https://doi.org/10.1007/s10973-018-7933-0
- Bisinella, V., Dahl, L., Jensen, H., Mikkelsen, T. and Christensen, T. (2021) Environmental Profile of NOx Reduction by a Photocatalytic Surface Coating and a Vehicle Catalytic Converter. Journal of Environmental Protection, 12, 590-623. https://doi.org/10.4236/jep.2021.129037
- Elavarasan, G. and Karthikeyyan, D. (2022) Cu-ZSM5 Zeolite as an Environmental Emission Reducing Catalyst for Biodiesel. International Journal of Environmental Science and Technology, 19, 5437-5450. https://doi.org/10.1007/s13762-021-03435-7
- Twigg, M.V. (2006) Roles of Catalytic Oxidation in Control of Vehicle Exhaust Emissions. Catalysis Today, 117, 407-418. https://doi.org/10.1016/j.cattod.2006.06.044
- Gendy, T., Zakhary, A. and Ghoneim, S. (2021) Response Surface Methodology and Artificial Neural Network Methods Comparative Assessment for Fuel Rich and Fuel Lean Catalytic Combustion. World Journal of Engineering and Technology, 9, 816-847. https://doi.org/10.4236/wjet.2021.94057
- Kalavrouziotis, T.V. and Koukoulakis, P.H. (2008) The Environmental Impact of the Platinum Group Elements (Pd, Pd, Rh) Emitted by the Automobile Catalyst Converters. Water, Air, & Soil Pollution, 196, 393-402. https://doi.org/10.1007/s11270-008-9786-9
- Laura, R.-L., Rubén, D.-V., Eloísa, T.-J., Gorazd, B. and Luka, L. (2023) Recent Advances in the Development of Automotive Catalytic Converters: A Systematic Review. Energies, 16, Article 6425. https://doi.org/10.3390/en16186425
- Shibata, S., Furukawa, M. and Goto, K. (1969) Dual-Wavelength Spectrophotometry. Analytica Chimica Acta, 46, 271-279. https://doi.org/10.1016/S0003-2670(01)95628-4
- Butcher, D. (2017) Recent Highlights in Graphite Furnace Atomic Absorption Spectrometry. Applied Spectroscopy Reviews, 52, 755-773. https://doi.org/10.1080/05704928.2017.1303504