CI Acid Orange 52 Dye Removal Using Natural and Formulated Clay-Lime Materials: Isotherm, Kinetic and Thermodynamic Studies — Oak Academic Publishing
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CI Acid Orange 52 Dye Removal Using Natural and Formulated Clay-Lime Materials: Isotherm, Kinetic and Thermodynamic Studies
Laboratory of Applied Physical and Analytical Chemistry, Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, Yaoundé ,Cameroon
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Inorganic and Physical Chemistry Lab, CSIR-Central Leather Research Institute, Chennai, India
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Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon
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Laboratory of Applied Physical and Analytical Chemistry, Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, Yaoundé ,Cameroon
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Laboratory of Applied Physical and Analytical Chemistry, Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, Yaoundé ,Cameroon
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Laboratory of Applied Physical and Analytical Chemistry, Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, Yaoundé ,Cameroon
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Laboratory of Applied Physical and Analytical Chemistry, Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, Yaoundé ,Cameroon
1 Laboratory of Applied Physical and Analytical Chemistry, Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, Yaoundé ,Cameroon
2 Inorganic and Physical Chemistry Lab, CSIR-Central Leather Research Institute, Chennai, India
3 Department of Chemistry, Faculty of Science, University of Buea, Buea, Cameroon
4 Laboratory of Applied Physical and Analytical Chemistry, Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, Yaoundé ,Cameroon
5 Laboratory of Applied Physical and Analytical Chemistry, Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, Yaoundé ,Cameroon
6 Laboratory of Applied Physical and Analytical Chemistry, Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, Yaoundé ,Cameroon
7 Laboratory of Applied Physical and Analytical Chemistry, Department of Inorganic Chemistry, Faculty of Science, University of Yaoundé I, Yaoundé ,Cameroon
The main objective of the study is to improve the removal efficiency of Ourlago-kaolin (Kao), sodium montmorillonite (Na-MMT), and two formulated clay-lime (F13 and F23) towards CI Acid Orange 52 dye (AO52). F13 and F23 were obtained by chemical stabilization through thermal treatment at 300°C. Fourier Transform Infrared spectra showed different surface functional groups on the clay materials, X-ray diffraction patterns revealed the raw materials contain many crystalline phases, scanning electron microscopy micrographs showed the variation of the layered structures of different clay materials, energy dispersive X-Ray analysis micrographs revealed compositional information and thermogravimetric-differential scanning calorimetry curves indicated the higher weight loss of 11.26% and 11.38% were observed for F13 and F23 respectively. BET surface area analyzed gave 133.0071 m 2 • g − 1 for F13 and 132.34803 m 2 • g − 1 for F23. The optimum pH value was 2.0 for Kao and Na-MMT. The adsorption experiments indicated that F13 and F23 have the maximum uptake abilities of 7.8740 and 3.1645 mg • g − 1 , respectively, compared to Kao (0.8761 mg • g − 1 ) and Na-MMT (2.6178 mg • g − 1 ). The pseudo-second-order model well described the adsorption kinetic model of AO52 dye onto the overall samples; Langmuir and Freundlich’s isotherms appropriately described the uptake mechanism. The positive values of ∆ G° and negative value ∆ H° indicated that the adsorption process was spontaneous and endothermic for Na-MMT, and non-spontaneous and exothermic for Kao, F13, and F23 because of their positive values of ∆ G° and negative value of ∆ H°. The modified clays have higher adsorption capacities and better life cycles compared hence opening new avenues for efficient wastewater treatment.
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