Clay Materials for Ceramics Application from N’Djamena in the Chad Republic: Mineralogical, Physicochemical and Microstructural Characterization — Oak Academic Publishing
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Clay Materials for Ceramics Application from N’Djamena in the Chad Republic: Mineralogical, Physicochemical and Microstructural Characterization
Department of Civil Engineering, National Advanced School of Engineering, University of Maroua, Maroua, Cameroon
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Department of Civil Engineering, National Advanced School of Engineering, University of Maroua, Maroua, Cameroon
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Department of Mining Engineering, School of Geology and Mining Engineering, University of Ngaoundere, Meiganga, Cameroon
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Department of Civil Engineering, National Advanced School of Engineering, University of Maroua, Maroua, Cameroon
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Local Materials Authority Promotion (MIPROMALO), Yaoundé, Cameroon
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Department of Environmental Sciences, Advanced School of Agriculture, Forestry, Water and Environment, University of Ebolowa, Ebolowa, Cameroon
1 Department of Civil Engineering, National Advanced School of Engineering, University of Maroua, Maroua, Cameroon
2 Department of Civil Engineering, National Advanced School of Engineering, University of Maroua, Maroua, Cameroon
3 Department of Mining Engineering, School of Geology and Mining Engineering, University of Ngaoundere, Meiganga, Cameroon
4 Department of Civil Engineering, National Advanced School of Engineering, University of Maroua, Maroua, Cameroon
5 Local Materials Authority Promotion (MIPROMALO), Yaoundé, Cameroon
6 Department of Environmental Sciences, Advanced School of Agriculture, Forestry, Water and Environment, University of Ebolowa, Ebolowa, Cameroon
Herein, we report some characteristics of the clayey materials (CMs) collected from Kaliwa (C1), Kabé (C2) and Malo (C3) district in N’Djamena (Chad). Three samples were characterized applying XRF, XRD, FTIR, SEM. In addition, TGA/DSC were performed to control decomposition/mass loss and show phase transitions respectively of CMs. Geochemical analysis by XRF reveals the following minerals composition: SiO 2 (~57% - 66%), Al 2 O 3 (~13% - 15%), Fe 2 O 3 (~6% - 10%), TiO 2 (~1% - 2%) were the predominant oxides with a reduced proportion in C1, and (~7%) of fluxing agents (K 2 O, CaO, Na 2 O). Negligible and trace of MgO (~1%) and P 2 O 5 was noted. The mineralogical composition by XRD shows that, C1, C2 and C3 display close mineralogy with: Quartz (~50%), feldspar (~20%) as non-clay minerals, whereas clays minerals were mostly kaolinite (~15%), illite (~5%) and smectite (~10%). FTIR analysis exhibits almost seemingly similar absorption bands characteristic of hydroxyls elongation, OH valence vibration of Kaolinite and stretching vibration of some Metal-Oxygen bond. SEM micrographs of the samples exhibit microstructureformed by inter-aggregates particles with porous cavities. TGA/DSCconfirm the existence of quartz (570 ˚ C to 870 ˚ C), carbonates (600 ˚ C - 760 ˚ C), kaolinite (569 ˚ C - 988 ˚ C), illite (566 ˚ C - 966 ˚ C), MgO (410 ˚ C - 720 ˚ C) and smectite (650 ˚ C - 900 ˚ C). The overall characterization indicates that, these clayey soils exhibit good properties for ceramic application.
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