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Some Salicylato New Organotin (IV) and Copper Chloride Adducts and Derivative: Synthesis and Spectroscopic Study
Département de Chimie Laboratoire de Chimie Minérale et Analytique, Faculté des Sciences et Techniques, Université Cheikh Anta Diop de Dakar, Dakar, Sénégal
Département de Chimie Laboratoire de Chimie Minérale et Analytique, Faculté des Sciences et Techniques, Université Cheikh Anta Diop de Dakar, Dakar, Sénégal
Département de Chimie Laboratoire de Chimie Minérale et Analytique, Faculté des Sciences et Techniques, Université Cheikh Anta Diop de Dakar, Dakar, Sénégal
Département de Chimie Laboratoire de Chimie Minérale et Analytique, Faculté des Sciences et Techniques, Université Cheikh Anta Diop de Dakar, Dakar, Sénégal
- 1 Département de Chimie Laboratoire de Chimie Minérale et Analytique, Faculté des Sciences et Techniques, Université Cheikh Anta Diop de Dakar, Dakar, Sénégal
- 2 Département de Chimie Laboratoire de Chimie Minérale et Analytique, Faculté des Sciences et Techniques, Université Cheikh Anta Diop de Dakar, Dakar, Sénégal
- 3 Département de Chimie Laboratoire de Chimie Minérale et Analytique, Faculté des Sciences et Techniques, Université Cheikh Anta Diop de Dakar, Dakar, Sénégal
- 4 Département de Chimie Laboratoire de Chimie Minérale et Analytique, Faculté des Sciences et Techniques, Université Cheikh Anta Diop de Dakar, Dakar, Sénégal
Journal of Materials Science and Chemical Engineering·Volume 12 (2024)·Pages 13–17·Published 22 October 2024·DOI10.4236/msce.2024.1210002
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Abstract
Three new salicylate complexes and derivatives have been synthesized and studied by infrared, 119 Sn NMR and UV-visible spectroscopies. The suggested structures for the two compounds are discrete with NH-O and NH-Cl hydrogen bonds. The salicylate oxyanion is monochelating for the first salicylate compound with an octahedral tin (IV) centre and monodentate for the second salicylate compound, the environments around the tin centre being tetrahedral. For the cooper complex, the salicylate ligand is monochelating and the environments around the copper atom centre are tetrahedral.
KeywordsDiscrete StructuresHydrogen BondsMonochelating MonodentateOctahedral or Tetrahedral Environments
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