Thiosemicarbazone (E)-2(1-(2-Hydroxyphenyl) Hydrazine)-1-Carbothioamide: Spectroscopic Studies, Xray Diffractometer Characterization and Antioxydant Test — Oak Academic Publishing
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Thiosemicarbazone (E)-2(1-(2-Hydroxyphenyl) Hydrazine)-1-Carbothioamide: Spectroscopic Studies, Xray Diffractometer Characterization and Antioxydant Test
Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal
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Laboratoire de Chimie de Coordination Organique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal
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Laboratoire de Chimie de Coordination Organique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal
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Département de Chimie, Université Alioune Diop de Bambey, Diourbel, Senegal
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Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal
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Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal
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Institut des Matériaux Jean Rouxel de Nantes, Nantes, France
1 Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal
2 Laboratoire de Chimie de Coordination Organique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal
3 Laboratoire de Chimie de Coordination Organique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal
4 Département de Chimie, Université Alioune Diop de Bambey, Diourbel, Senegal
5 Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal
6 Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal
7 Institut des Matériaux Jean Rouxel de Nantes, Nantes, France
In the present work, a new semithiocarbazone ligand C 3 NH 4 CONHNC(CH 3 ) C 6 H 4 OH H 4 L 2 have been isolated and characterized by single-crystal X-ray diffraction. Compound H 4 L 2 crystallizes in the monoclinic system space group P21/n with a = 10.9328(9), b = 8.1700(6), c = 13.8095(11) Å, β = 93.7591(14)˚, V = 3671.57(9) Å 3 , Z = 16, Z’ = 2. Semithiocarbazone connected through NH···O and OH···O hydrogen bonds. In the crystal, the structure is organized in layer-like arrangements. Structural characterizations were completed by infrared and 1 H, 13 C{ 1 H} spectroscopy and elemental analysis which corroborate the X-ray elucidations. In another case, this organic compound is submitted to antioxidant test. The test has been done by using Akhtar et al. methods [1] with some modifications. The tests are done with different concentration of solutions between 100 to 500 μM. The values of per cent of inhibition (5.18% - 25.90%) of the solution containing semithiocarbazone organic compound show a real difference compared to the values of the reference TROLOX. These results show that our organic ligand C 3 NH 4 CONHNC(CH 3 )C 6 H 4 OH is a good antioxidant compound.
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