The removal of arsenic from water is essential for the protection of public health. To investigate the adsorption capabilities of laterite, sandstone, and shale for the removal of arsenic from aqueous solutions, column experiments were conducted. In this study, raw materials and heat-treated (calcined) materials were examined. The experiments assessed the influence of various parameters, including initial concentration, bed depth, and the effects of heat treatment. The findings revealed that the breakthrough curves were influenced by the initial concentration of arsenic, the depth of the bed, and the type of material used. For an initial arsenic concentration of 5 mg/L, columns containing 85 cm of calcined laterite, sandstone, and shale produced volumes of 7460 ml (1492 min), 3510 ml (702 min), and 4400 ml (880 min) of water with arsenic levels below 0.01 mg/L, respectively. These calcined materials demonstrate significant potential for the effective removal of arsenic from water.
KeywordsGeomaterialsAdsorptionArsenicWater
Styblo, M. and Douillet, C. (2016) Diabetes Mellitus. In: States, J.C., Ed., Exposure Sources , Health Risks , and Mechanisms of Toxicity . Epidemiology and Disease Manifestations of Arsenic Exposure , Wiley, 221-248.
Fatoki, J.O. and Badmus, J.A. (2022) Arsenic as an Environmental and Human Health Antagonist: A Review of Its Toxicity and Disease Initiation. Journal of Hazardous Materials Advances , 5, Article 100052. https://doi.org/10.1016/j.hazadv.2022.100052
Sevak, P. and Pushkar, B. (2024) Arsenic Pollution Cycle, Toxicity and Sustainable Remediation Technologies: A Comprehensive Review and Bibliometric Analysis. Journal of Environmental Management , 349, Article 119504. https://doi.org/10.1016/j.jenvman.2023.119504
Ahoulé, D.G., Lalanne, F., Mendret, J., Brosillon, S. and Maïga, A.H. (2015) Arsenic in African Waters: A Review. Water , Air , & Soil Pollution , 226, Article No. 302. https://doi.org/10.1007/s11270-015-2558-4
Boutenègre, L., Marpaux, L. and Rullan, R. (2021) Apologie d’un poison: L’arsenic, propriétés et applications. JPCE ENS de Lyon , 4, 3-12.
Mann, K.K. and Lemaire, C. (2016) Role in Chemotherapy. In: States, J.C., Ed., Exposure Sources , Health Risks , and Mechanisms of Toxicity . Mechanisms of Toxicity , Wiley, 113-126.
Mangoua-Allali, A.L.C., Koua-Koffi, A., Akpo, K.S. and Coulibaly, L. (2015) Evaluation of Water and Sanitation Situation of Rural Area near Landfill, Abidjan. Journal of Chemical , Biological and Physical Sciences , 5, 3033-3041.
Mondal, P., Balomajumder, C. and Mohanty, B. (2007) A Laboratory Study for the Treatment of Arsenic, Iron, and Manganese Bearing Ground Water Using Fe 3+ Impregnated Activated Carbon: Effects of Shaking Time, pH and Temperature. Journal of Hazardous Materials , 144, 420-426. https://doi.org/10.1016/j.jhazmat.2006.10.078
Harisha, R.S., Hosamani, K.M., Keri, R.S., Nataraj, S.K. and Aminabhavi, T.M. (2010) Arsenic Removal from Drinking Water Using Thin Film Composite Nanofiltration Membrane. Desalination , 252, 75-80. https://doi.org/10.1016/j.desal.2009.10.022
George, C.M., Smith, A.H., Kalman, D.A. and Steinmaus, C.M. (2006) Reverse Osmosis Filter Use and High Arsenic Levels in Private Well Water. Archives of Environmental & Occupational Health , 61, 171-175. https://doi.org/10.3200/aeoh.61.4.171-175
Altundoğan, H.S., Altundoğan, S., Tümen, F. and Bildik, M. (2002) Arsenic Adsorption from Aqueous Solutions by Activated Red Mud. Waste Management , 22, 357-363. https://doi.org/10.1016/s0956-053x(01)00041-1
Omer, O.S., Hussein, B.H.M., Hussein, M.A. and Mgaidi, A. (2017) Mixture of Illite-Kaolinite for Efficient Water Purification: Removal of As(III) from Aqueous Solutions. Desalination and Water Treatment , 79, 273-281. https://doi.org/10.5004/dwt.2017.20801
Chakravarty, S., Dureja, V., Bhattacharyya, G., Maity, S. and Bhattacharjee, S. (2002) Removal of Arsenic from Groundwater Using Low Cost Ferruginous Manganese Ore. Water Research , 36, 625-632. https://doi.org/10.1016/s0043-1354(01)00234-2
Coulibaly, S.L., Yvon, J. and Coulibaly, L. (2015) Physicochemical Characterization of Lomo Nord Black Shale and Application as Low Cost Material for Phosphate Adsorption in Aqueous Solution. Journal of Environmental & Earth Sciences , 5, 42-60.
Coulibaly, L.S., Akpo, S.K., Yvon, J. and Coulibaly, L. (2016) Fourier Transform Infra-Red (FTIR) Spectroscopy Investigation, Dose Effect, Kinetics and Adsorption Capacity of Phosphate from Aqueous Solution onto Laterite and Sandstone. Journal of Environmental Management , 183, 1032-1040. https://doi.org/10.1016/j.jenvman.2016.09.061
Koua-Koffi, N.A.A., Coulibaly, L.S., Sangare, D. and Coulibaly, L. (2018) Laterite, Sandstone and Shale as Adsorbents for the Removal of Arsenic from Water. American Journal of Analytical Chemistry , 9, 340-352. https://doi.org/10.4236/ajac.2018.97027
Ezzati, G., Healy, M.G., Christianson, L., Daly, K., Fenton, O., Feyereisen, G., et al . (2020) Use of Rapid Small-Scale Column Tests for Simultaneous Prediction of Phosphorus and Nitrogen Retention in Large-Scale Filters. Journal of Water Process Engineering , 37, Article 101473. https://doi.org/10.1016/j.jwpe.2020.101473
Koua-Koffi, N.A.A., Coulibaly, L.S., Mangoua-Allali, L.C. and Coulibaly, L. (2018) Utilization of Calcined Sandstone and Calcined Laterite as an Adsorbent for the Removal of Arsenic from Water. Journal of Environmental & Earth Sciences , 8, 81-93.
Koua-Koffi, N.A.A., Coulibaly, L.S., Sangare, D. and Coulibaly, L. (2021) Removal of Arsenic from Simulated Groundwater Using Calcined Shale as the Adsorbent. International Research Journal of Pure and Applied Chemistry , 22, 31-39. https://doi.org/10.9734/irjpac/2021/v22i630414
Maleki, F., Muthukrishnan, N., Ovens, K., Reinhold, C. and Forghani, R. (2020) Machine Learning Algorithm Validation. Neuroimaging Clinics of North America , 30, 433-445. https://doi.org/10.1016/j.nic.2020.08.004
Ortega, R., Loria, A. and Kelly, R. (1995) A Semiglobally Stable Output Feedback PI/sup 2/D Regulator for Robot Manipulators. IEEE Transactions on Automatic Control , 40, 1432-1436. https://doi.org/10.1109/9.402235
Hasan, S.H., Ranjan, D. and Talat, M. (2010) Agro-Industrial Waste ‘Wheat Bran’ for the Biosorptive Remediation of Selenium through Continuous Up-Flow Fixed-Bed Column. Journal of Hazardous Materials , 181, 1134-1142. https://doi.org/10.1016/j.jhazmat.2010.05.133
Badruzzaman, M., Westerhoff, P. and Knappe, D.R.U. (2004) Intraparticle Diffusion and Adsorption of Arsenate onto Granular Ferric Hydroxide (GFH). Water Research , 38, 4002-4012. https://doi.org/10.1016/j.watres.2004.07.007
Nguyen, P.T.N., Abella, L.C., Gaspillo, P.D. and Hinode, H. (2011) Removal of Arsenic from Simulated Groundwater Using Calcined Laterite as the Adsorbent. Journal of Chemical Engineering of Japan , 44, 411-419. https://doi.org/10.1252/jcej.11we025
Sanou, Y., Kabore, R. and Pare, S. (2020) Adsorption of Arsenic and Phosphate from Groundwater onto a Calcined Laterite as Fixed Bed in Column Experiments. French-Ukrainian Journal of Chemistry , 8, 227-243. https://doi.org/10.17721/fujcv8i2p227-243
Sarkar, M., Banerjee, A., Pramanick, P.P. and Sarkar, A.R. (2006) Use of Laterite for the Removal of Fluoride from Contaminated Drinking Water. Journal of Colloid and Interface Science , 302, 432-441. https://doi.org/10.1016/j.jcis.2006.07.001
Tan, I.A.W., Ahmad, A.L. and Hameed, B.H. (2008) Adsorption of Basic Dye Using Activated Carbon Prepared from Oil Palm Shell: Batch and Fixed Bed Studies. Desalination , 225, 13-28. https://doi.org/10.1016/j.desal.2007.07.005
Han, R., Wang, Y., Zhao, X., Wang, Y., Xie, F., Cheng, J., et al . (2009) Adsorption of Methylene Blue by Phoenix Tree Leaf Powder in a Fixed-Bed Column: Experiments and Prediction of Breakthrough Curves. Desalination , 245, 284-297. https://doi.org/10.1016/j.desal.2008.07.013
Sadaf, S. and Bhatti, H.N. (2013) Evaluation of Peanut Husk as a Novel, Low Cost Biosorbent for the Removal of Indosol Orange RSN Dye from Aqueous Solutions: Batch and Fixed Bed Studies. Clean Technologies and Environmental Policy , 16, 527-544. https://doi.org/10.1007/s10098-013-0653-z
Roy, P., Mondal, N.K., Bhattacharya, S., Das, B. and Das, K. (2013) Removal of arsenic(III) and arsenic(V) on Chemically Modified Low-Cost Adsorbent: Batch and Column Operations. Applied Water Science , 3, 293-309. https://doi.org/10.1007/s13201-013-0082-5
Maji, S.K., Kao, Y., Wang, Y. and Liu, C. (2014) Dynamic Column Adsorption of as on Iron-Oxide-Coated Natural Rock (IOCNR) and Sludge Management. Desalination and Water Treatment , 55, 2171-2182. https://doi.org/10.1080/19443994.2014.928912
Omitola, O.B., Abonyi, M.N., Akpomie, K.G. and Dawodu, F.A. (2022) Adams-Bohart, Yoon-Nelson, and Thomas Modeling of the Fix-Bed Continuous Column Adsorption of Amoxicillin onto Silver Nanoparticle-Maize Leaf Composite. Applied Water Science , 12, Article No. 94. https://doi.org/10.1007/s13201-022-01624-4
Mondal, M.K. (2009) Removal of Pb(II) Ions from Aqueous Solution Using Activated Tea Waste: Adsorption on a Fixed-Bed Column. Journal of Environmental Management , 90, 3266-3271. https://doi.org/10.1016/j.jenvman.2009.05.025
Yu, J., Qi, L., Cheng, B. and Zhao, X. (2008) Effect of Calcination Temperatures on Microstructures and Photocatalytic Activity of Tungsten Trioxide Hollow Microspheres. Journal of Hazardous Materials , 160, 621-628. https://doi.org/10.1016/j.jhazmat.2008.03.047
Valix, M. and Cheung, W.H. (2002) Study of Phase Transformation of Laterite Ores at High Temperature. Minerals Engineering , 15, 607-612. https://doi.org/10.1016/s0892-6875(02)00068-7
Jeon, E., Ryu, S., Park, S., Wang, L., Tsang, D.C.W. and Baek, K. (2018) Enhanced Adsorption of Arsenic onto Alum Sludge Modified by Calcination. Journal of Cleaner Production , 176, 54-62. https://doi.org/10.1016/j.jclepro.2017.12.153
Pal, B.N. (2001) Granular Ferric Hydroxide for Elimination of Arsenic from Drinking Water. In: Ahmed, M.F., Ali, M.A. and Adeel, Z., Eds., Technologies for Arsenic Removal from Drinking Water , Bangladesh University of Engineering and Technology and United Nations University, 59-68.