Characterization of Local Clay from Burkina Faso for the Removal of Lead from Groundwater — Oak Academic Publishing
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Characterization of Local Clay from Burkina Faso for the Removal of Lead from Groundwater
Equipe Physico-Chimie et de Technologie des Matériaux, Laboratoire de Chimie Moléculaire et des Matériaux (LCMM), Unité de Formation et de Recherche en Sciences Exactes et Appliquées (UFR-SEA), Université Joseph KI-ZERBO, Ouagadougou, Burkina Faso
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Équipe Chimie Physique et électrochimie, Laboratoire de Chimie Moléculaire et des Matériaux (LCMM), Unité de Formation et de Recherche en Sciences Exactes et Appliquées (UFR-SEA), Université Joseph KI-ZERBO, Ouagadougou, Burkina Faso
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Equipe Physico-Chimie et de Technologie des Matériaux, Laboratoire de Chimie Moléculaire et des Matériaux (LCMM), Unité de Formation et de Recherche en Sciences Exactes et Appliquées (UFR-SEA), Université Joseph KI-ZERBO, Ouagadougou, Burkina Faso
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Direction de la Recherche Géologique et Minière (DRGM), Bureau des Mines et de la Géologie du Burkina (BUMIGEB), Ouagadougou, Burkina Faso
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Kaya University Center, Joseph KI-ZERBO University, Ouagadougou, Burkina Faso
1 Equipe Physico-Chimie et de Technologie des Matériaux, Laboratoire de Chimie Moléculaire et des Matériaux (LCMM), Unité de Formation et de Recherche en Sciences Exactes et Appliquées (UFR-SEA), Université Joseph KI-ZERBO, Ouagadougou, Burkina Faso
2 Équipe Chimie Physique et électrochimie, Laboratoire de Chimie Moléculaire et des Matériaux (LCMM), Unité de Formation et de Recherche en Sciences Exactes et Appliquées (UFR-SEA), Université Joseph KI-ZERBO, Ouagadougou, Burkina Faso
3 Equipe Physico-Chimie et de Technologie des Matériaux, Laboratoire de Chimie Moléculaire et des Matériaux (LCMM), Unité de Formation et de Recherche en Sciences Exactes et Appliquées (UFR-SEA), Université Joseph KI-ZERBO, Ouagadougou, Burkina Faso
4 Direction de la Recherche Géologique et Minière (DRGM), Bureau des Mines et de la Géologie du Burkina (BUMIGEB), Ouagadougou, Burkina Faso
5 Kaya University Center, Joseph KI-ZERBO University, Ouagadougou, Burkina Faso
The contamination of water resources by trace metals (TMs), particularly lead (Pb 2+ ), is a significant public health and environmental concern, especially in areas where access to modern treatment technologies is limited. The adsorbent material used is KOM clay, collected from Kombissiri, near Ouagadougou, in Burkina Faso, and characterized using various physicochemical techniques. Characterization enabled the quantification of the minerals present in KOM: quartz (27%), montmorillonite (25%), illite (21%), kaolinite (18%), and goethite (6%). This characterization highlighted the adsorbent properties of montmorillonite clay, which endow it with an interesting adsorption capacity for removing lead from groundwater. Adsorption tests carried out in synthetic batch solutions showed that the adsorption capacity of lead (Pb 2+ ) is influenced by various parameters, namely kinetics, dose effect, and initial concentration effect. The kinetic study showed that contact time is reached after 3 hours. The data were consistent with the pseudo-second-order model. The results obtained by dose effect show that clay could remove up to 98.03%, or 4.9 mg/g, for an optimal adsorbent dose of 10 g/L. The isotherm models obtained from the data on the effect of the initial concentration on the adsorption of lead Pb 2+ confirmed that the adsorption of lead Pb 2+ is monolayer adsorption. This result reflects a strong affinity between lead and the active sites of montmorillonite and confirms the value of this natural material as an economical and sustainable solution for treating water polluted by trace metals.
Kieufack, G., Fagel, N., Tchamba, A.B., Bomeni, I.Y., Ngapgue, F., El Ouahabi, M., et al. (2023) Mineralogical and Physico-Chemical Characterization of Alluvial Clays from Bamendou-Balessing (West Cameroon): Suitability for Ceramics. Construction and Building Materials , 407, Article ID: 133396. https://doi.org/10.1016/j.conbuildmat.2023.133396
Sorgho, B., Paré, S., Guel, B., Zerbo, L., Traoré, K. and Persson, I. (2011) Etude d’une argile locale du Burkina Faso à des fins de décontamination en Cu 2+ , Pb 2+ et Cr 3+ . Journal de la Société Ouest-Africaine de Chimie , 31, 49-59.
Ukhurebor, K.E., Aigbe, U.O., Onyancha, R.B., Nwankwo, W., Osibote, O.A., Paumo, H.K., et al. (2021) Effect of Hexavalent Chromium on the Environment and Removal Techniques: A Review. Journal of Environmental Management , 280, Article ID: 111809. https://doi.org/10.1016/j.jenvman.2020.111809
Qlihaa, A., Dhimni, S., Melrhaka, F., Hajjaji, N. and Srhiri, A. (2016) Caractérisation physico-chimique d’une argile Marocaine [Physico-Chemical Characterization of a Morrocan Clay]. Journal of Materials and Environmental Science , 7, 1741-1750. https://www.jmaterenvironsci.com/Document/vol7/vol7_N5/192-JMES-2132-Qlihaa.pdf
Mekbel, S., Messaouda, D. and Ammar, N. (2024) Effets de l’argile et des boues sur le retrait et la porosité des briques : Etude comparative. International Society for Soil Mechanics and Geotechnical Engineering (ISSMGE). https://www.issmge.org/publications/online-library
Mimanne, G., Benhabib, K., Benghalem, A. and Taleb, S. (2014) Etude de l’Adsorption des Métaux Lourds (Pb et Cd) en Solution Aqueuse sur Charbon Actif et Montmorillonite Sodée de l’Ouest Algérien [Study of the Adsorption of Heavy Metals (Pb and Cd) in Aqueous Solution on Activated Carbon and Sodium Montmorillonite from Western Algeria]. Journal of Materials and Environmental Science , 5, 1298-1307. https://www.jmaterenvironsci.com/Document/vol5/vol5_N4/159-JMES-888-2014-Mimanne.pdf
Imbga, B.K., Sorgho, B., Kabore, B. and Sambou, V. (2023) Caractéristiques thermiques d’une argile Kaolinite stabilisée avec la gousse de Néré en vue de l’isolation thermique de l’enveloppe du bâtiment dans la zone sahélienne. Journal de Physique de la SOAPHYS , 3, C23N55-1-C23N55-7. https://doi.org/10.46411/jpsoaphys.2023.018
Kouadio, L.M., Lebouachera, S.E.I., Blanc, S., Sei, J., Miqueu, C., Pannier, F., et al. (2022) Characterization of Clay Materials from Ivory Coast for Their Use as Adsorbents for Wastewater Treatment. Journal of Minerals and Materials Characterization and Engineering , 10, 319-337. https://doi.org/10.4236/jmmce.2022.104023
Generalova, A., Davidova, S. and Satchanska, G. (2025) The Mechanisms of Lead Toxicity in Living Organisms. Journal of Xenobiotics , 15, Article 146. https://doi.org/10.3390/jox15050146
Njopwouo, D. and Orliac, M. (1979) Note sur le comportement de certains minéraux A l’attaque triacide. In: Cahiers de l ’ ORSTOM , série Pédologie , XVII, ORSTOM, 329-337.
Ouedraogo, R.D., Bakouan, C., Sorgho, B., Guel, B. and Bonou, L.D. (2020) Caractérisation d’une latérite naturelle du Burkina Faso en vue de l’élimination de l’arsenic (III) et l’arsenic (V) dans les eaux souterraines. International Journal of Biological and Chemical Sciences , 13, 2959-2977. https://doi.org/10.4314/ijbcs.v13i6.41
Saeed, M., Munir, M., Nafees, M., Shah, S.S.A., Ullah, H. and Waseem, A. (2020) Synthesis, Characterization and Applications of Silylation Based Grafted Bentonites for the Removal of Sudan Dyes: Isothermal, Kinetic and Thermodynamic Studies. Microporous and Mesoporous Materials , 291, Article ID: 109697. https://doi.org/10.1016/j.micromeso.2019.109697
Taha, A.A., Shreadah, M.A., Ahmed, A.M. and Heiba, H.F. (2016) Multi-Component Adsorption of Pb(II), Cd(II), and Ni(II) onto Egyptian Na-Activated Bentonite; Equilibrium, Kinetics, Thermodynamics, and Application for Seawater Desalination. Journal of Environmental Chemical Engineering , 4, 1166-1180. https://doi.org/10.1016/j.jece.2016.01.025
Fayoud, N., Younssi, S.A., Tahiri, S. and Albizane, A. (2015) Etude cinétique et thermodynamique de l’adsorption de bleu de méthylène sur les cendres de bois. Journal of Materials and Environmental Science , 6, 3295-3306.
Ennajih, H. (2014) Synthèse de nouveaux surfactants pour la modification des argiles, étude et caractérisation des nanocomposites et biocomposites produits. Thèse de doctorat, Université Mohammed V, Agdal. https://toubkal.imist.ma/handle/123456789/13068
Pleşa Chicinaş, R., Bedelean, H., Stefan, R. and Măicăneanu, A. (2018) Ability of a Montmorillonitic Clay to Interact with Cationic and Anionic Dyes in Aqueous Solutions. Journal of Molecular Structure , 1154, 187-195. https://doi.org/10.1016/j.molstruc.2017.10.038
Taha, A.A., Shreadah, M.A., Heiba, H.F. and Ahmed, A.M. (2017) Validity of Egyptian Na‐montmorillonite for Adsorption of Pb 2+ , Cd 2+ and Ni 2+ under Acidic Conditions: Characterization, Isotherm, Kinetics, Thermodynamics and Application Study. Asia-Pacific Journal of Chemical Engineering , 12, 292-306. https://doi.org/10.1002/apj.2072
Cai, J., Lei, M., Zhang, Q., He, J., Chen, T., Liu, S., et al. (2017) Electrospun Composite Nanofiber Mats of Cellulose@Organically Modified Montmorillonite for Heavy Metal Ion Removal: Design, Characterization, Evaluation of Absorption Performance. Composites Part A : Applied Science and Manufacturing , 92, 10-16. https://doi.org/10.1016/j.compositesa.2016.10.034
Garcia-Valles, M., Alfonso, P., Martínez, S. and Roca, N. (2020) Mineralogical and Thermal Characterization of Kaolinitic Clays from Terra Alta (Catalonia, Spain). Minerals , 10, Article 142. https://doi.org/10.3390/min10020142
Muwawa, J., Seke Vangu, M., Kayembe Sungula, J., Sola, D., Nkodi Mananga, T., Pongo Pongo, H., et al. (2024) Physicochemical Characterization by AXRF and XRD Analysis of Clays Samples from Bulungu, Kwilu Province, Democratic Republic of Congo. Journal Africain des Sciences , 1, 64-69. https://doi.org/10.70237/jafrisci.2024.v1.i2.08
Costa, T.C.d.C., Melo, J.D.D. and Paskocimas, C.A. (2013) Thermal and Chemical Treatments of Montmorillonite Clay. Ceramics International , 39, 5063-5067. https://doi.org/10.1016/j.ceramint.2012.11.105
Kouadio, L. M. (2023) Contribution à l’évaluation des niveaux de contamination des eaux et des sols des sites d’orpaillage clandestin et élimination des métaux (Hg, Pb, Cd) et de l’arsenic des eaux polluées, à l’aide des argiles de Côte d’Ivoire. Thèse de Doctorat, Université Felix Houphouët-Boigny, 1-232. https://hal.science/tel-04148757
Sorgho, B., Bressollier, P., Guel, B., Zerbo, L., Ouedraogo, R., Gomina, M., et al. (2016) Étude des propriétés mécaniques des géomateriaux argileux associant la décoction de Parkia Biglobosa (néré). Comptes Rendus . Chimie , 19, 895-901. https://doi.org/10.1016/j.crci.2016.01.016
Munvuyi, D., Ousmane, M.S. and Bougouma, M. (2022) Physicochemical and Mineralogical Characterization of Clays from the Tcheriba Zone in the Boucle of Mouhoun Region (Burkina Faso). Journal of Materials and Environmental Science , 13, 755-767. http://www.jmaterenvironsci.com
Messeaouda, S. (2015) Etude de la capacité de rétention et d’élimination des cations métalliques par des adsorbants naturels. Thèse de Doctorat, Université de Mustapha Stambouli, 184 p. http://dspace.univ-mascara.dz:8080/jspui/handle/123456789/142.
Ahmad, R. and Hasan, I. (2015) L-Cystein Modified Bentonite-Cellulose Nanocomposite (Cellu/Cys-Bent) for Adsorption of Cu 2+ , Pb 2+ , and Cd 2+ Ions from Aqueous Solution. Separation Science and Technology , 51, 381-394. https://doi.org/10.1080/01496395.2015.1095211
Lacaran, J.V.T., Narceda, R.J., Bilo, J.A.V. and Leaño Jr., J.L. (2021) Citric Acid Crosslinked Nanofibrillated Cellulose from Banana (Musa Acuminata X Balbisiana) Pseudostem for Adsorption of Pb 2+ and Cu 2+ in Aqueous Solutions. Cellulose Chemistry and Technology , 55, 403-415. https://doi.org/10.35812/cellulosechemtechnol.2021.55.38
Gallouze, H., Akretche, D., Daniel, C., Coelhoso, I. and Crespo, J.G. (2021) Removal of Synthetic Estrogen from Water by Adsorption on Modified Bentonites. Environmental Engineering Science , 38, 4-14. https://doi.org/10.1089/ees.2020.0048
Kedi, A.B.B., Kouassi, S.S., Coulibaly, V. and Sei, J. (2021) Elimination de polluants des déchets liquides d’une unité de production de sucre par des argiles naturelles de Côte d’Ivoire. International Journal of Biological and Chemical Sciences , 15, 803-815. https://doi.org/10.4314/ijbcs.v15i2.31
Amor, G., & Bagane, M. (2021) Optimisation de l’adsorption du plomb et du zinc en solution bicomposé sur une argile activée par la méthode des plans d’expériences. I OSR Journal of Engineering , 11, 2250-3021.