Homogeneous Isolation of Nanocellulose from Cotton Cellulose by High Pressure Homogenization
- 1 1Agriculture Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, China; College of Food Science and Technology of Huazhong Agricultural University, Wuhan, China
- 2 Agriculture Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, China
- 3 Agriculture Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, China; National Center of Important Tropical Crops Engineering and Technology Research, Haikou, China
- 4 Agriculture Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, China; National Center of Important Tropical Crops Engineering and
- 5 Agriculture Products Processing Research Institute, Chinese Academy of Tropical Agricultural Sciences, Zhanjiang, China
- 6 Institute for Frontier Materials, Deakin University, Waurn Ponds, Vic, Australia
Abstract
Nano-cellulose materials are widely believed to have the potential to push polymer mechanical properties. The cotton cellulose was dissolved in ionic liquid (1-butyl-3-methylimidazolium chloride ([Bmim]Cl)), and then was isolated by high pressure homogenization in a homogeneous media. The nano-cellulose was obtained at 80MPa for 30 cycles. The geometry and microstructure of the cellulose nano-fibres were observed by SEM and their particle size analysis. FTIR, XRD and TGA were used to characterize changes to chemical functionality. Particular emphasis is given to the physical and chemical characterization of these nano-fibres together with their thermal stability and crystallinity, in order to develop their suitability.
- U.-J. Kim, et al., “Thermal Decomposition of Native Cellulose Influence on Crystallite Size,” Polymer Degradation and Stability, Vol. 95, 2010, pp. 778-781. http://dx.doi.org/10.1016/j.polymdegradstab.2010.02.009
- D. Klemm, et al., “Cellulose: Fascinating Biopolymer and Sustainable Raw Material,” Angewandte Chemie International Edition, Vol. 44, No. 3, 2005, pp. 3358-3393. http://dx.doi.org/10.1021/bm201176m
- A. Kljun, et al., “Comparative Analysis of Crystallinity Changes in Cellulose I Polymers Using ATR-FTIR, X-Ray Diffraction, and Carbohydrate-Binding Module Probes,” Biomacromolecules, Vol. 12, No. 11, 2011, pp. 4121-4126. http://dx.doi.org/10.1021/bm201176m
- J. Li, et al., “Homogeneous Isolation of Nanocellulose from Sugarcane Bagasse by High Pressure Homogenization,” Carbohydrate Polymers, Vol. 90, No. 4, 2012, pp. 1609-1613. http://dx.doi.org/10.1016/j.carbpol.2012.07.038
- Z. Man, et al., “Preparation of Cellulose Nanocrystals Using an Ionic Liquid,” Journal of Polymers and the Environment, Vol. 44, No. 3, 2005, pp. 3358-3393.
- S. Marchesan and M. Prato, “Nanomaterials for (Nano) Medicine,” ACS Medicinal Chemistry Letters, Vol. 4, No. 2, 2013, pp. 147-149. http://dx.doi.org/10.1021/ml3003742
- N. Muhammad, et al., “Effect of Ionic Liquid Treatment on Pyrolysis Products from Bamboo,” Industrial & Engineering Chemistry Research, Vol. 51, 2012, pp. 2280- 2289. http://dx.doi.org/10.1021/ie2014313
- K. Nakashima, et al., “Direct Bioethanol Production from Cellulose by the Combination of Cellulose-Displaying Yeast and Ionic Liquid Pretreatment,” Green Chemistry, Vol. 13, 2011, pp. 2948-2953. http://dx.doi.org/10.1039/c1gc15688h
- E. H. Qua, et al., “Preparation and Characterization of Cellulose Nanofibres,” Journal of Materials Science, Vol. 46, No. 18, 2011, pp. 6029-6045. http://dx.doi.org/10.1007/s10853-011-5565-x
- Y. Yue, et al., “Comparative Properties of Cellulose Nano-Crystals from Native and Mercerized Cotton Fibers,” Cellulose, Vol. 19, 2012, pp. 1173-1187. http://dx.doi.org/10.1021/ma0505676
- H. Zhang, J. Wu, J. Zhang and J. S. He, “1-Allyl-3-Methylimidazolium Chloride Room Temperature Ionic Liquid: A New and Powerful Nonderivatizing Solvent for Cellulose,” Macromolecules, Vol. 38, 2005, pp. 8272- 8277. http://dx.doi.org/10.1021/ma0505676
- L. Zhang, D. Ruan and S. J. Gao, “Dissolution and Regeneration of Cellulose in NaOH/Thiourea Aqueous Solution,” Polymer Science, Vol. 4, 2002, pp. 1521-1529. http://dx.doi.org/10.1002/polb.10215