Graphite Nanoplatelets Composite Materials: Role of the Epoxy-System in the Thermal Conductivity — Oak Academic Publishing
Research ArticleOpen AccessGoogle Scholar indexed
Graphite Nanoplatelets Composite Materials: Role of the Epoxy-System in the Thermal Conductivity
Laboratoire Charles Coulomb (L2C), UMR 5221 CNRS-Université de Montpellier, Montpellier, Université Lyon 1, Lyon, France
,
Laboratoire Charles Coulomb (L2C), UMR 5221 CNRS-Université de Montpellier, Montpellier, Université Lyon 1, Lyon, France
,
Laboratoire Charles Coulomb (L2C), UMR 5221 CNRS-Université de Montpellier, Montpellier, Université Lyon 1, Lyon, France
,
Laboratoire Charles Coulomb (L2C), UMR 5221 CNRS-Université de Montpellier, Montpellier, Université Lyon 1, Lyon, France
,
Laboratoire Charles Coulomb (L2C), UMR 5221 CNRS-Université de Montpellier, Montpellier, Université Lyon 1, Lyon, France
,
Materials and Solid Insulation Architect-Energy BU/Medium Voltage Switchgear, Schneider Electric, Grenoble, France
,
Laboratorio de Materiales para Tecnologías Emergentes, Centro de Investigación en Tecnología de los Materiales, Instituto Venezolano de Investigaciones Científicas, Maracaibo, Venezuela
,
Laboratorio de Materiales para Tecnologías Emergentes, Centro de Investigación en Tecnología de los Materiales, Instituto Venezolano de Investigaciones Científicas, Maracaibo, Venezuela
1 Laboratoire Charles Coulomb (L2C), UMR 5221 CNRS-Université de Montpellier, Montpellier, Université Lyon 1, Lyon, France
2 Laboratoire Charles Coulomb (L2C), UMR 5221 CNRS-Université de Montpellier, Montpellier, Université Lyon 1, Lyon, France
3 Laboratoire Charles Coulomb (L2C), UMR 5221 CNRS-Université de Montpellier, Montpellier, Université Lyon 1, Lyon, France
4 Laboratoire Charles Coulomb (L2C), UMR 5221 CNRS-Université de Montpellier, Montpellier, Université Lyon 1, Lyon, France
5 Laboratoire Charles Coulomb (L2C), UMR 5221 CNRS-Université de Montpellier, Montpellier, Université Lyon 1, Lyon, France
6 Materials and Solid Insulation Architect-Energy BU/Medium Voltage Switchgear, Schneider Electric, Grenoble, France
7 Laboratorio de Materiales para Tecnologías Emergentes, Centro de Investigación en Tecnología de los Materiales, Instituto Venezolano de Investigaciones Científicas, Maracaibo, Venezuela
8 Laboratorio de Materiales para Tecnologías Emergentes, Centro de Investigación en Tecnología de los Materiales, Instituto Venezolano de Investigaciones Científicas, Maracaibo, Venezuela
Polymers typically have intrinsic thermal conductivity much lower than other materials. Enhancement of this property may be obtained by the addition of conductive fillers. In this research, epoxy nanocomposites with exfoliated graphite nanoplatelets are prepared and characterized. The chosen approach requires no surface treatment and no sophisticated equipments allowing one to produce composites on a pilot scale. A significant increase of the thermal conductivity with the increasing of the graphite fillers content is nevertheless observed on 4 mm thick specimens. Our results viewed in the latest scientific findings suggest that the choice of resin is an important parameter to move towards composite materials with high thermal conductivity.
Koci, V. and Loubal, T. (2012) LCA of Liquid Epoxy Resin Produced Based on Propylene and on Glycerine. Acta Environmentalica Universitatis Comenianae, 20, 62-67. http://staryweb.fns.uniba.sk/index.php?id=4281
Ebadi-Dehaghani, H. and Nazempour, M. (2012) Smart Nanoparticles: Thermal Conductivity of Nanoparticles Filled Polymers, [online]; Intech (Ed.), Chapter 23, 519-533.
King, J.A., Tucker, K.W., Vogt, B.D., Weber, E.H. and Quan, C. (1999) Electrically and Thermally Conductive Nylon 6,6. Polymer Composites, 20, 643-654. http://dx.doi.org/10.1002/pc.10387
Han, Z. and Fina, A. (2011) Thermal Conductivity of Carbon Nanotubes and Their Polymer Nanocomposites: A Review. Progress in Polymer Science, 36, 914-944. http://dx.doi.org/10.1016/j.progpolymsci.2010.11.004
Shahill, K.M.F. and Balandin, A. (2012) Graphene-Multilayer Grapheme Nanocomposites as Highly Efficient Thermal Interface materials. Nano Letters, 12, 861-867. http://dx.doi.org/10.1021/nl203906r
Balandin, A. (2011) Thermal Properties of Graphene and Nanostructured Carbon Materials. Nature Materials, 10, 569- 581. http://dx.doi.org/10.1038/nmat3064
Segal, M. (2009) Selling Grapheme by the Ton. Nature Nanotech, 4, 612-614. http://dx.doi.org/10.1038/nnano.2009.279
Pizza, A., Metz, R., Hassanzadeh, M. and Bantignies, J-L. (2014) Life Cycle Assessment of Nanocomposites Made of Thermally Conductive Graphite Nanoplatelets. The International Journal of Life Cycle Assessment, 19, 1226-1237. http://dx.doi.org/10.1007/s11367-014-0733-2
He, Y. (2005) Rapid Thermal Conductivity Measurement with a Hot Disk Sensor. Part 1: Theoretical Considerations. Thermochimica Acta, 436, 122-129. http://dx.doi.org/10.1016/j.tca.2005.06.026
He, Y. (2005) Rapid Thermal Conductivity Measurement with a Hot Disk Sensor. Part 2: Characterization of Thermal Greases. Thermochimica Acta, 436, 130-134. http://dx.doi.org/10.1016/j.tca.2005.07.003
Li, M., Wilkinson, D. and Patchigolla, K. (2005) Comparison of Particle Size Distributions Measured Using Different Techniques. Particulate Science and Technology, 23, 265-284. http://dx.doi.org/10.1080/02726350590955912
Debelak, B. and Lafdi, K. (2007) Use of Exfoliated Graphite Filler to Enhance Polymer Physical Properties. Carbon, 45, 1727-1734. http://dx.doi.org/10.1016/j.carbon.2007.05.010
Chatterjee, S., Wang, J.W., Kuo, W.S., Tai, N.H., Salzmann, C., Li, W.L., Hollertz, R., Nüesch, F.A. and Chu, B.T.T. (2012) Mechanical Reinforcement and Thermal Conductivity in Expanded Graphene Nanoplatelets Reinforced Epoxy Composites. Chemical Physics Letters, 531, 6-10. http://dx.doi.org/10.1016/j.cplett.2012.02.006
Zheng, C., Fan, Z.J., Wei, T. and Luo, G.L. (2009) Temperature Dependence of the Conductivity Behavior of Graphite Nanoplatelet-Filled Epoxy Resin Composites. Journal of Applied Polymer Science, 113, 1515-1519. http://dx.doi.org/10.1002/app.30009
Yu, A., Ramesh, P., Itkis, M.E., Bekyarova, E. and Haddon, R.C. (2007) Graphite Nanoplatelet-Epoxy Composite Thermal Interface Materials. Journal of Physical Chemistry C, 111, 7565-7569. http://dx.doi.org/10.1021/jp071761s
Ganguli, S., Roy, A.K. and Anderson, D.P. (2008) Improved Thermal Conductivity for Chemically Functionalized Exfoliated Graphite/Epoxy Composites. Carbon, 46, 806-817. http://dx.doi.org/10.1016/j.carbon.2008.02.008
Prolongo, S.G., Moriche, R., Jiménez-Suárez, A., Sanchez, M. and Urena, A. (2014) Advantages and Disadvantages of the Addition of Graphene Nanoplatelets to Epoxy Resins. European Polymer Journal, 61, 206-214. http://dx.doi.org/10.1016/j.eurpolymj.2014.09.022
Min, C., Yu, D.M., Cao, J.Y., Wang, G.L. and Feng, L.H. (2013) A Graphite Nanoplatelet/Epoxy Composite with High Dielectric Constant and High Thermal Conductivity. Carbon, 55, 116-125. http://dx.doi.org/10.1016/j.carbon.2012.12.017
Chandrasekaran, S., Seidel, C. and Schulte, K. (2013) Preparation and Characterization of Graphite Nano-Platelet (GNP)/Epoxy Nano-Composite: Mechanical, Electrical and Thermal Properties. European Polymer Journal, 49, 3878- 3888. http://dx.doi.org/10.1016/j.eurpolymj.2013.10.008
Loos, M., Coelho, L. and Pezzin, S. (2008) The Effect of Acetone Addition on the Properties of Epoxy. Polímeros: Ciencia e Tecnologia, 18, 76-80.