Research ArticleOpen AccessGoogle Scholar indexed
Synthesis and Characterization of Lithium Manganese Oxide with Different Ratio of Mole on Lithium Recovery Process from Ge-othermal Fluid of Lumpur Sidoarjo
Department of Materials and Metallurgical Engineering, Sepuluh Nopember Institute of Technology, Surabaya, Indonesia
Department of Materials and Metallurgical Engineering, Sepuluh Nopember Institute of Technology, Surabaya, Indonesia
Department of Materials and Metallurgical Engineering, Sepuluh Nopember Institute of Technology, Surabaya, Indonesia
Department of Geophysical Engineering, Sepuluh Nopember Institute of Technology, Surabaya, Indonesia
- 1 Department of Materials and Metallurgical Engineering, Sepuluh Nopember Institute of Technology, Surabaya, Indonesia
- 2 Department of Materials and Metallurgical Engineering, Sepuluh Nopember Institute of Technology, Surabaya, Indonesia
- 3 Department of Materials and Metallurgical Engineering, Sepuluh Nopember Institute of Technology, Surabaya, Indonesia
- 4 Department of Geophysical Engineering, Sepuluh Nopember Institute of Technology, Surabaya, Indonesia
Journal of Materials Science and Chemical Engineering·Volume 03 (2015)·Pages 56–62·Published 13 November 2015·DOI10.4236/msce.2015.311007
Copy link · social · email
Abstract
Geothermal fluid of Lumpur Sidoarjo (Lusi) with lithium content as high as 5.81 mg/liter has a great potential as the source of lithium. Lithium recovery from geothermal liquid of Lusi is firstly investigated by adsorption methods with Lithium Manganese Oxide (LMO) as absorbent. LMO is considered as a promising candidate of adsorbent material due to non-toxic and low cost production. LMOs with different ratio of mole are prepared by solid state reactions method at temperature 500?C for 5 hrs. XRD peaks of pre- and post-acid treatment LMO 1, 0.8 and 0.5 show a stable spinel crystal structure while LMO 2 has monoclinic structure. The highest lithium adsorption capability is obtained by LMO 1 with 6.6 mg/g.
KeywordsLithium Manganese OxideAdsorbentLithium RecoveryGeothermal FluidLumpur Sidoarjo
- Jaskula, B.W. (2013) Lithium: U.S. Geological Survey Mineral Commodity Summaries. USGS National Minerals Information Center, Virginia, 94-95.
- David, R.J., Simon, S.A., Swarbrick, R.E. and Tingay, M.J. (2010) Probabilistic Longevity Estimate for the LUSI Mud Volcano, East Java. Journal of the Geological Society, 168, 517-523.
- Tanikawa, W. (2011) The Mechanism of Overpressure Generation in the LUSI Mud Volcano. E-Proceeding Symposium on Future Lusi, BPLS.
- Ooi, K., Miyai, Y. and Katoh, S. (1986) Recovery of Lithium from Seawater by Manganese Oxide Adsorbent. Separation Science and Technology, 21, 755-766.
- Chitrakar, R., Kanoh, H., Miyai, Y. and Ooi, K. (2001) Recovery of Lithium from Seawater Using Manganese Oxide Adsorbent (H1.6Mn1.6O4) Derivied from Li1.6Mn1.6O. Industrial & Engineering Chemistry Research, 40, 2054-2058. http://dx.doi.org/10.1021/ie000911h
- Kitajou, A., Suzuki, T., Nishihama, S. and Yoshizuka, K. (2003) Selective Recovery of Lithium From Seawater Using a Novel MnO2 Adsorbent II-Enhancement of Lithium Ion Selectivity of The Adsorbent. Ars Separatoria Acta, 2, 97-106.
- Wang, L., Ma, W., Liu, R., Li, H.Y. and Meng, C.C. (2006) Correlation between Li+ Adsorption Capacity and the Preparation Conditions of Spinel Lithium Manganese Precursor. Solid State Ionics, 177, 1421-1428. http://dx.doi.org/10.1016/j.ssi.2006.07.019
- David, W.I.F., Thackeray, M.M., Bruce, P.G. and Goodenough, J.B. (1984) Lithium Insertion Into β-MnO2 and The Rutile-Spinel Transformation. Materials Research Bulletin, 19, 99-106. http://dx.doi.org/10.1016/0025-5408(84)90015-1
- Chung, K.-S., Lee, J.-C., Kim, W.-K., Kim, S.B. and Cho, K.Y. (2008) Inorganic Adsorbent Containing Polymeric Membrane Reservoir for the Recovery of Lithium from Seawater. Journal of Membrane Science, 325, 503-508. http://dx.doi.org/10.1016/j.memsci.2008.09.041
- Hunter, J.C. (1981) Preparation of a New Crystal Form of Manganese Dioxide: λ-MnO2. Journal of Solid State Chemistry, 3, 142-147. http://dx.doi.org/10.1016/0022-4596(81)90323-6
- Chung, K., Lee, J., Kim, E., Lee, K., Kim, Y. and Ooi, K. (2004) Recovery of Lithium from Seawater Using Nano-Manganese Oxide Adsorbents Prepared by Gel Process. Materials Science Forum, 449-452, 277-280. http://dx.doi.org/10.4028/www.scientific.net/MSF.449-452.277
- Ammundsen, B., Aitchison, P.B., Burns, G.R., Jones, D.J. and Roziere, J. (1997) Proton Insertion and Lithium-Proton Exchange in Spinel Lithium Manganates. Solid State Ionics, 97, 269-276. http://dx.doi.org/10.1016/S0167-2738(97)00065-9