Polypyrrole/porphyrin nanohybrid (PPy/Tpp(OH) 4 nanohybrid) have been synthesized through a self-assembled approach, and the assynthesized PPy/Tpp(OH) 4 nanohybrid are characterized by Fourier-transform infrared, X-ray photoelectron spectroscopy, Raman spectroscopy, thermogravimetric analysis, Ultraviolet-visible absorption, scanning electron microscopy, and steady state fluorescence spectroscopic techniques. Formation of the PPy/Tpp(OH) 4 nanohybrid dramatically improved the solubility and processability of the PPy-based nanomaterial. The nonlinear optical (NLO) properties of PPy/Tpp(OH) 4 nanohybrid were measured by Z-scan at 532 nm with nanosecond laser pulse, the results indicating that PPy/Tpp(OH) 4 nanohybrid exhibits a enhanced NLO property in comparison with the benchmark PPy and Tpp(OH) 4 due to a combination of mechanisms.
Torre, G.D.L., Vazquez, P., Lopez, F.A. and Torres, T. (2004) Role of Structural Factors in the Nonlinear Optical Properties of Phthalocyanines and Related Compounds. Chemical Reviews, 104, 3723-3750. https://doi.org/10.1021/cr030206t
Zhang, L. and Wang, L. (2008) Recent Research Progress on Optical Limiting Property of Materials Based on Phthalocyanine, Its Derivatives, and Carbon Nanotubes. Journal of Materials Science, 43, 5692-5701. https://doi.org/10.1007/s10853-008-2826-4
Sajeev, U.S., Nambuthiri, V.V., Salah, A., Nampoori, V.P.N. and Anantharaman, M.R. (2010) Studies on the Nonlinear Optical Properties of RF Plasma Polymerized Aniline thin Films by Open Aperture z-Scan Technique. Synthetic Metals, 160, 15-16. https://doi.org/10.1016/j.synthmet.2010.06.004
Lanzi, M. and Paganin, L. (2009) New Photosetting NLO-Active Polythiophenes with Enhanced Optical Stability. European Polymer Journal, 45, 1118-1126. https://doi.org/10.1016/j.eurpolymj.2009.01.013
Ke, R., Zhang, X.M., Zhang, S.Y., Li, S.L., Mao, C.J., Niu, H.L., Song, J.M. and Tian, Y.P. (2015) Self-Catalytic Polymerization of Water-Soluble Selenium/Polypyrrole Nanocomposite and Its Nonlinear Optical Properties. Physical Chemistry Chemical Physics, 17, 27548-27557. https://doi.org/10.1039/C5CP04419G
Zhou, C., Zhang, Y.W., Li, Y.Y. and Liu, J.P. (2013) Construction of High-Capacitance 3D CoO@Polypyrrole Nanowire Array Electrode for Aqueous Asymmetric Supercapacitor. Nano Letters, 13, 2078-2085. https://doi.org/10.1021/nl400378j
Song, W.N., He, C.Y., Dong, Y.L., Zhang, W., Gao, Y.C., Wu, Y.Q. and Chen, Z.M. (2015) The Effects of Central Metals on the Photophysical and Nonlinear Optical Properties of Reduced Graphene Oxide-Metal(II) Phthalocyanine Hybrids. Physical Chemistry Chemical Physics, 17, 7149-7157. https://doi.org/10.1039/C4CP05963H
Ye, Y.S., Chen, Y.N., Wang, J.S., Rick, J., Huang, Y.J., Chang, F.C. and Hwang, B.J. (2012) Versatile Grafting Approaches to Functionalizing Individually Dispersed Graphene Nanosheets Using RAFT Polymerization and Click Chemistry. Chemistry of Materials, 24, 2987-2997. https://doi.org/10.1021/cm301345r
Luo, S.L., Liu, X.E., Wu, D.Q., Shi, G. and Mei, T. (2014) Tunable Conversion from Saturable Absorption to Reverse Saturable Absorption in Poly(pyrrole methine) Derivatives. Journal of Material Chemistry C, 2, 8850-8853. https://doi.org/10.1039/C4TC01627K
Scandola, F., Chiorboli, C., Prodi, A., Iengo, E. and Alessio, E. (2006) Photophysical Properties of Metal-Mediated Assemblies of Porphyrins. Coordination Chemistry Reviews, 250, 1471-1496. https://doi.org/10.1016/j.ccr.2006.01.019
Imahori, H. and Fukuzumi, S. (2004) Porphyrin-and Fullerene-Based Molecular Photovoltaic Devices. Advanced Functional Materials, 14, 525-536. https://doi.org/10.1002/adfm.200305172
Wang, J.J., Zhou, Z.J., Bai, Y., Liu, Z.B., Li, Y., Wu, D., Chen, W., Li, Z.R. and Sun, C.C. (2012) The Interaction between Superalkalis (M3O, M = Na, K) and a C20F20 Cage Forming Superalkali Electride Salt Molecules with Excess Electrons inside the C20F20 Cage: Dramatic Superalkali Effect on the Nonlinear Optical Property. Journal of Material and Chemistry, 22, 9652-9657. https://doi.org/10.1039/c2jm15405f
Huang, C., Hu, C.L., Xu, X., Yang, B.P. and Mao, J.G. (2013) Tl(VO)2O2(IO3)3: A New Polar Material with a Strong SHG Response. Dalton Transactions, 42, 7051-7058. https://doi.org/10.1039/c3dt33107e
Liu, C.G. and Guan, X.H. (2013) Computational Study on Redox-Switchable Second-Order Nonlinear Optical Properties of Totally Inorganic Keggin-Type Polyoxometalate Complexes. Journal of Physical Chemistry C, 117, 7776-7783. https://doi.org/10.1021/jp400185a
Wang, Y.Q., Shi, Y., Pan, L.J., Ding, Y., Zhao, Y., Li, Y., Shi, Y. and Yu, G.H. (2015) Dopant-Enabled Supramolecular Approach for Controlled Synthesis of Nanostructured Conductive Polymer Hydrogels. Nano Letters, 15, 7736-7741. https://doi.org/10.1021/acs.nanolett.5b03891
Liu, Y.N., Jin, J.Y., Deng, H.P., Li, K., Zheng, Y.L., Yu, C.Y. and Zhou, Y.F. (2016) Protein-Framed Multi-Porphyrin Micelles for a Hybrid Natural-Artificial Light-Harvesting Nanosystem. Angewandte Chemie, 128, 8084-8089. https://doi.org/10.1002/ange.201601516
Wang, A.J., Long, L.L., Zhao, W., Song, Y.L., Humphrey, M.G., Cifuentes, M.P., Wu, X.Z., Fu, Y.S., Zhang, D.D., Li, X.F. and Zhang, C. (2013) Increased Optical Nonlinearities of Graphene Nanohybrids Covalently Functionalized by Axially-Coordinated Porphyrins. Carbon, 53, 327-338.
Jain, S., Karmakar, N., Shah, A., Kothari, D.C., Mishra, S. and Shimpi, N.G. (2017) Ammonia Detection of 1-D ZnO/Polypyrrole Nanocomposite: Effect of CSA Doping and Their Structural, Chemical, Thermal and Gas Sensing Behavior. Applied Surface Science, 396, 1317-1325.
Mao, H., Ji, C.G., Liu, M.H., Sun, Y., Liu, D.L., Wu, S.Y., Zhang, Y. and Song, X.M. (2016) Hydrophilic Polymers/Polypyrrole/Graphene Oxide Nanosheets with Different Performance in Electrocatalytic Application to Simultaneous Determination of Dopamine and Ascorbic Acid. RSC Advances, 6, 11632-11639. https://doi.org/10.1039/C6RA23341D
Tabaciarova, J., Micusík, M., Fedorko, P. and Omastova, M. (2015) Study of Polypyrrole Aging by XPS, FTIR and Conductivity Measurements. Polymer Degradation and Stability, 120, 392-401.
Khadka, R., Aydemir, N., Kesküla, A., Tamm, T., Travas-Sejdic, J. and Kiefer, R. (2017) Enhancement of Polypyrrole Linear Actuation with Poly(Ethylene Oxide). Synthetic Metals, 232, 1-7.
Gong, F., Xu, X., Zhou, G. and Wang, Z.S. (2013) Enhanced Charge Transportation in a Polypyrrole Counter Electrode via Incorporation of Reduced Graphene Oxide Sheets for Dye-Sensitized Solar Cells. Physical Chemistry Chemical Physics, 15, 546-552. https://doi.org/10.1039/C2CP42790G
Wang, A.J., Yu, W., Xiao, Z.G., Song, Y.L., Long, L.L., Cifuentes, M.P., Humphery, M.G. and Zhang, C. (2015) A 1,3-Dipolar Cycloaddition Protocol to Porphyrinfunctionalized Reduced Graphene Oxide with a Push-Pull Motif. Nano Research, 8, 870-886. https://doi.org/10.1007/s12274-014-0569-x
Wang, A.J., Yu, W., Huang, Z.P., Zhou, F., Song, J.B, Song, Y.L., Long, L.L., Cifuentes, M.P., Humphery, M.G., Zhang, L., Shao, J.D. and Zhang, C. (2015) Covalent Functionalization of Reduced Graphene Oxide with Porphyrin by Means of Diazonium Chemistry for Nonlinear Optical Performance. Scientific Reports, 6, 1-12.
Wang, J.J., Feng, M. and Zhan, H.B. (2013) Preparation, Characterization, and Nonlinear Optical Properties of Graphene Oxide-Carboxymethyl Cellulose Composite Films. Optics & Laser Technology, 57, 84-89.
Liu, M.Q., Zhao, J., Xiao, C.F., Quan, Q. and Li, X.F. (2016) PPy-Assisted Fabrication of Ag/TiO2 Visible-Light Photocatalyst and Its Immobiliza-tion on PAN Fiber. Materials and Design, 104, 428-435.
Balakumar, V. and Prakash, P. (2016) A Facile in Situ Synthesis of Highly Active and Reusable Ternary Ag-PPy-GO Nanocomposite for Catalytic Oxidation of Hydroquinone in Aqueous Solution. Journal of Catalysis, 344, 795-805.
Yang, K., Gu, M.Y., Guo, Y.P., Pan, X.F. and Mu, G.H. (2009) Effects of Carbon Nanotube Functionalization on the Mechanical and Thermal Properties of Epoxy Composites. Carbon, 47, 1723-1737.
Jaouhari, A.E., Filotas, D., Laabd, M., Kiss, A., Bazzaoui, E.A., Nagy, L., Nagy, G., Albourine, A., Martins, J.I., Wang, R. and Bazzaoui, M. (2016) SECM Investigation of Electrochemically Synthesized Polypyrrole from Aqueous Medium. Journal of Applied Electrochemistry, 46, 1199-1209. https://doi.org/10.1007/s10800-016-1002-9
Osmieri, L., Videla, A.H.A.M. and Specchia, S. (2016) Optimization of a FeeNeC Electrocatalyst Supported on Mesoporous Carbon Functionalized with Polypyrrole for Oxygen Reduction Reaction under Both Alkaline and Acidic Conditions. International Journal of Hydrogen Energy, 41, 19610-19628.
Yan, J., Huang, Y., Chen, X.F. and Wei, C. (2016) Conducting Polymers-NiFe2O4 Coated on Reduced Graphene Oxide Sheets as Electromagnetic (EM) Wave Absorption Materials. Synthetic Metals, 221, 291-298.
Zhu, J.H., Li, Y.X., Chen, Y., Wang, J., Zhang, B., Zhang, J.J. and Blau, W.J. (2011) Graphene Oxide Covalently Functionalized with Zinc Phthalocyanine for Broadband optical Limiting. Carbon, 49, 1900-1905.
Li, C.L., Chen, N., Zhao, Y.N., Li, R. and Feng, C.P. (2016) Polypyrrole-Grafted Peanut Shell Biological Carbon as a Potential Sorbent for Fluoride Removal: Sorption Capability and Mechanism. Chemosphere, 163, 81-89.
Wang, A.J., Song, J.B, Huang, Z.P., Song, Y.L., Yu, W., Dong, H.L., Hu, W.P., Cifuentes, M.P., Humphery, M.G., Zhang, L., Shao, J.D. and Zhang, C. (2015) Multi-Walled Carbon Nanotubes Covalently Functionalized by Axially Coordinated Metal-Porphyrins: Facile Syntheses and Temporally Dependent Optical Performance. Nano Research, 9, 458-472. https://doi.org/10.1007/s12274-015-0928-2
Wang, A.J., Fang, Y., Long, L.L., Song, Y.L., Yu, W., Zhao, W., Cifuentes, M.P., Humphrey, M.G. and Zhang, C. (2013) Facile Synthesis and Enhanced Nonlinear Optical Properties of Porphyrin-Functionalized Multi-Walled Carbon Nanotubes. Chemistry A European Journal, 19, 14159-14170. https://doi.org/10.1002/chem.201302477
Hedge, P.K., Adhikari, A.V., manjunatha, M.G., Sandeep, C.S.S. and Philip, R. (2010) A New Donor-Acceptor Type Conjugative Poly{2-[4-(1-Cyanoethenyl) phe-nyl]-3-(3,4-didodecyloxythiophen-2-yl)prop-2-enenitrile}: Synthesis and NLO Studies. Synthesitic Metals, 160, 15-16.
Liu, Z.B., Guo, Z., Zhang, X.L., Zheng, J.Y. and Tian, J.G. (2013) Increased Optical Nonlinearities of Multi-Walled Carbon Nanotubes Covalently Functionalized with Porphyrin. Carbon, 51, 419-426.
Krisshna, M.B.M., Venkatramaiah, N., Venkatesan, R. and Rao, D.N. (2012) Synthesis and Structural, Spectroscopic and Nonlinear Optical Measurements of Graphene Oxide and Its Composites with Metal and Metal Free Porphyrins. Journal of Material Chemistry, 22, 3059-3068. https://doi.org/10.1039/c1jm14822b
Wang, L., Chen, T.L. and Jiang, J.Z. (2014) Controlling the Growth of Porphyrin Based Nanostructures for Tuning Third-Order NLO Properties. Nanoscale, 6, 1871-1878. https://doi.org/10.1039/C3NR05140D
Pandey, R.K., Sandeep, C.S.S., Philip, R. and Lakshminarayanan, V. (2009) Enhanced Optical Nonlinearity of Polyaniline-Porphyrin Nanocomposite. Journal of Physical Chemistry C, 113, 8630-8634. https://doi.org/10.1021/jp808691v
Huang, C.S., Li, Y.L., Song, Y.L, Li, Y.J., Liu, H.B. and Zhu, D.B. (2010) Ordered Nanosphere Alignment of Porphyrin for the Improvement of Nonlinear Optical Properties. Advanced Materials, 22, 3532-3536. https://doi.org/10.1002/adma.200904421
Gupta, J., Vijayan, C., Mauurya, S.K. and Goswami, D. (2012) Ultrafast Nonlinear Optical Response of Carbon Nanotubes Functionalized with Water Soluble Porphyrin. Optics Communications, 285, 1920-1924.
Nalla, V., Polavarapu, L., Manga, K.K., Goh, B.M., Loh, K.P., Xu, O.H. and Ji, W. (2010) Transient Photoconductivity and Femtosecond Nonlinear Optical Properties of a Conjugated Polymer-Graphene Oxide Composite. Nanotechnology, 21, 415203-415209. https://doi.org/10.1088/0957-4484/21/41/415203
Hiroshi, H. and Sakata, Y. (1997) Donor-Linked Fullerenes: Photoinduced Electron Transfer and Its Potential Application. Advanced Materials, 9, 537-546. https://doi.org/10.1002/adma.19970090704
Anusha, P.T., Swain, D., Hamad, S., Giribabu, L., Prashant, T.S., Tewari, S.P. and Rao, S.V. (2012) Ultrafast Excited-State Dynamics and Dispersion Studies of Third Order Optical Nonlinearities in Novel Corroles. The Journal of Physical Chemistry C, 116, 17828-17837. https://doi.org/10.1021/jp305497b
Krishna, M.B.M., kumer, V.P., Venkatramaiah, N., Venkatesan, R. and Rao, D.N. (2011) Nonlinear Optical Properties of Covalently Linked Graphene-Metal Porphyrin Composite Materials. Applied Physics Letters, 98, Article No. 08116. https://doi.org/10.1063/1.3553500