Nicotinamide Inhibition Properties for Copper Corrosion in 3.5% NaCl Solution: Experimental and Theorical Investigations

Abstract

This work reports the inhibition properties of nicotinamide (NAM) for copper protection during its applications in seawater systems such as water pipelines, shipbuilding, seawater desalination and heat exchange systems. The efficiency of NAM as a copper corrosion inhibitor in simulated seawater (3.5% NaCl solution) was investigated by Tafel extrapolation and linear polarization methods in the temperature range from 20 ℃ to 50 ℃ . The corrosion parameters and the adsorption isotherms were determined using potentiodynamic polarization techniques. It was found that the inhibition efficiency ( η ) and the coverage rate ( θ ) increase up 80% at 25℃ for nicotinamide concentration of 10 mM but decrease as the temperature of the solution increases. Moreover, the obtained thermodynamic parameters using Langmuir model suggested a physical adsorption type. A correlation was found between the corrosion inhibition efficiency and the global theoretical parameters obtained by the functional density method B3LYP/ 6-31 + G (d, p). Local parameters such as condensed Fukui functions [ f ( r )] and condensed local softness [ s ( r )] indices have also been determined to obtain a chemical insight into atoms that have a significant tendency toward donation or acceptance of whole or fraction of electrons.