This paper reports obtaining of useful and high-value materials from sesame seed cake (SSC). For this purpose, SSC sample was burned for 30 s using Nd: YAG laser with output power 60 W. The products of this process and non-burned SSC were characterized by X-ray diffractometer (XRD), energy dispersive x-ray (EDX) and Fourier transform infrared (FTIR) so as to investigate its crystal structure and chemical components. XRD results of the SSC before burning process showed amorphous silica, rhombohedral phase of carbon, monoclinic phase of aluminum chloride, the hexagonal phase of moissanite-4H, (yellow, black) and hexagonal phase of graphite-2H, C (black). While the results of the burned SSC sample showed that the burning process using the power of Nd: YAG laser cased in appearing of crystalline hexagonal phase for silica and Carbon Nitride and converting the rhombohedral phase of Carbon into hexagonal phase. FTIR showed a number of absorbance peaks assigned to silica.
Zhang, Z., Gonzalez, A.M., Davies, E.G. and Liu, Y. (2012) Agricultural Wastes. Water Environment Research, 84, 1386-1406. https://doi.org/10.2175/106143012X13407275695193
Eshenaur, W., Collins, E., Goodrich, P.R. and Wulfe, M. (1984) Understanding Agricultural Waste Recycling: Volunteers in Technical Assistance.
Mehta, A. and Ugwekar, R. (2015) Extraction of Silica and Other Related Products from Rice Husk. International Journal of Engineering Research and Applications, 5, 95-98.
Della, V.P., Kühn, I. and Hotza, D. (2002) Rice Husk Ash as an Alternate Source for Active Silica Production. Materials Letters, 57, 818-821. https://doi.org/10.1016/S0167-577X(02)00879-0
Liou, T.-H. (2004) Preparation and Characterization of Nano-Structured Silica from Rice Husk. Materials Science and Engineering: A, 364, 313-323. https://doi.org/10.1016/j.msea.2003.08.045
de Sousa, A.M., Visconte, L., Mansur, C. and Furtado, C. (2009) Silica Sol Obtained from Rice Husk Ash. 3, 321-326.
Ghorbani, F., Sanati, A.M. and Maleki, M. (2015) Production of Silica Nanoparticles from Rice Husk as Agricultural Waste by Environmental Friendly Technique. Environmental Studies of Persian Gulf, 2, 56-65.
Nandiyanto, A., Rahman, T., Fadhlulloh, M., Abdullah, A., Hamidah, I. and Mulyanti, B. (eds.) (2016) Synthesis of Silica Particles from Rice Straw Waste Using a Simple Extraction Method. IOP Conference Series: Materials Science and Engineering, 128, 12040. https://doi.org/10.1088/1757-899X/128/1/012040
Singh, D., Kumar, R., Kumar, A. and Rai, K. (2008) Synthesis And characterization of Rice Husk Silica, Silica-Carbon Composite and H3PO4 Activated Silica. Ceramica, 54, 203-212. https://doi.org/10.1590/S0366-69132008000200011
Naqvi, H., Saeed, A., Umair, A. and Tajwar, S. (2011) Precipitated Silica from Wheat Husk. Journal of Pakistan Institute of Chemical Engineers, 39, 51-54.
Chen, H., Wang, F., Zhang, C., Shi, Y., Jin, G., Yuan, S. (2010) Preparation of Nano-Silica Materials: The Concept from Wheat Straw. Journal of Non-Crystalline Solids, 356, 2781-2785. https://doi.org/10.1016/j.jnoncrysol.2010.09.051
Naqvi, J., Shah, F. and Mansha, M. (2011) Extraction of Amorphous Silica from Wheat Husk by Using KMnO4. Journal of Faculty of Engineering & Technology, 18, 39-46.
Gawbah, M.A.P., Marouf, A.A., Alsabah, Y.A., Orsod, M.U. and Elbadawi, A.A. (2017) Synthesis of Silica, Silicon Carbide and Carbon from Wheat Bran and Converting Its Crystal Structure Using Nd: YAG Laser. International Journal of Advanced in Physical Science, 4, 31-37.
Habeeb, G.A. and Mahmud, H.B. (2010) Study on Properties of Rice Husk Ash and Its Use as Cement Replacement Material. Materials Research, 13, 185-190. https://doi.org/10.1590/S1516-14392010000200011
Suja, K., Jayalekshmy, A. and Arumughan, C. (2005) Antioxidant Activity of Sesame Cake Extract. Food Chemistry, 91, 213-219. https://doi.org/10.1016/j.foodchem.2003.09.001
Bigoniya, P., Nishad, R. and Singh, C.S. (2012) Preventive Effect of Sesame Seed Cake on Hyperglycemia and Obesity against High Fructose-Diet Induced Type 2 Diabetes in Rats. Food Chemistry, 133, 1355-1361. https://doi.org/10.1016/j.foodchem.2012.01.112
Sarkis, J.R., Michel, I., Tessaro, I.C. and Marczak, L.D.F. (2014) Optimization of Phenolics Extraction from Sesame Seed Cake. Separation and Purification Technology, 122, 506-514. https://doi.org/10.1016/j.seppur.2013.11.036
Koechner, W. (2013) Solid-State Laser Engineering. Springer, Berlin.
Koechner, W. and Bass, M. (2006) Solid-State Lasers: A Graduate Text. Springer Science & Business Media, Berlin.
Shen, G., Rivers, M.L., Wang, Y. and Sutton, S.R. (2001) Laser Heated Diamond Cell System at the Advanced Photon Source for in Situ X-Ray Measurements at High Pressure and Temperature. Review of Scientific Instruments, 72, 1273-1282. https://doi.org/10.1063/1.1343867
Sun, L. and Gong, K. (2001) Silicon-Based Materials from Rice Husks and Their Applications. Industrial & Engineering Chemistry Research, 40, 5861-5877. https://doi.org/10.1021/ie010284b
Lender, P.W. and Ruiter, R. (1990) Novel Inorganic Materials and Heterogeneous Catalysis. Inorganic and Metal-Containing Polymeric Materials. Plenum Press, New York, 187-195.
Brinker, C.J. and Scherer, G.W. (2013) Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing. Academic Press, Cambridge.
Kailasam, K., Epping, J.D., Thomas, A., Losse, S. and Junge, H. (2011) Mesoporous Carbon Nitride-Silica Composites by a Combined Sol-Gel/Thermal Condensation Approach and Their Application as Photocatalysts. Energy & Environmental Science, 4, 4668-4674. https://doi.org/10.1039/c1ee02165f
Li, B. and Cao, H. (2011) ZnO@ Graphene Composite with Enhanced Performance for the Removal of Dye from Water. Journal of Materials Chemistry, 21, 3346-3349. https://doi.org/10.1039/C0JM03253K
Chen, J., Zhao, D., Jin, X., Wang, C., Wang, D. and Ge, H. (2014) Modifying Glass Fibers with Graphene Oxide: Towards High-Performance Polymer Composites. Composites Science and Technology, 97, 41-45. https://doi.org/10.1016/j.compscitech.2014.03.023
Sahoo, S., Seydibe-yoglu, M., Mohanty, A. and Misra, M. (2011) Characterization of Industrial Lignins for Their Utilization in Future Value Added Applications. Biomass and Bioenergy, 35, 4230-4237. https://doi.org/10.1016/j.biombioe.2011.07.009
Bellamy, L.J. (1975) Amides, Proteins and Polypeptides. The Infra-Red Spectra of Complex Molecules. Springer, Berlin, 231-262. https://doi.org/10.1007/978-94-011-6017-9_12
Chang, Q., Hao, X. and Duan, L. (2008) Synthesis of Crosslinked Starch-Graft-Polyacrylamide-Co-Sodium Xanthate and Its Performances in Wastewater Treatment. Journal of Hazardous Materials, 159, 548-553. https://doi.org/10.1016/j.jhazmat.2008.02.053