Syntheses, Structures and Properties of 3d-4f Heterometallic Coordination Polymers Based on Tetradentate Metalloligand and Lanthanoid Ions — Oak Academic Publishing
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Syntheses, Structures and Properties of 3d-4f Heterometallic Coordination Polymers Based on Tetradentate Metalloligand and Lanthanoid Ions
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, China
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School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, China
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School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, China
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China-Australia Joint Research Center for Functional Molecular Materials, Jiangsu University, Zhenjiang, China
1 School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, China
2 School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, China
3 School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, China
4 China-Australia Joint Research Center for Functional Molecular Materials, Jiangsu University, Zhenjiang, China
Based on tetradentate metalloligand L Cu ([Cu(2,4-pydca) 2 ], 2,4-pydca = pyridine-2,4-dicarboxylate) and lanthanides (Sm 3+ , Dy 3+ ), two 3d-4fheterometalliccoordination polymers, namely, {[Sm 2 (DMSO) 4 (CH 3 OH) 2 ][L Cu ] 3 ·7DMSO·2CH 3 OH} n 1 and {[Dy 2 (DMSO) 3 (CH 3 OH)][L Cu3 (DMSO)] · 4DMSO · CH 3 OH} n 2 (DMSO = dimethyl sulfoxide), have been synthesized and well characterized by elemental analysis, Fourier-transform infrared spectroscopy, thermogravimetric and single-crystal X-ray diffraction analysis. Single-crystal X-ray analysis reveals that both 1 and 2 crystallize in the triclinic crystal system with P -1 space group and possess the 3D framework structures, which are constructed from metalloligands L Cu connecting with {Sm 2 } and {Dy 2 } clusters, respectively. The 3D structure of 1 has a 6-connected single-nodal topology with the point symbol {4 9 × 6 6 }, while 2 features a different framework with the point symbol of {4 12 × 6 3 }. Thermogravimetric analysis exhibits that the skeleton of both 1 and 2 collapse after 350℃. Magnetic properties of 1 and 2 have also been investigated.
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