The Approximate Analytical Solution of Non-Linear Equation for Simultaneous Internal Mass and Heat Diffusion Effects
- 1 Department of Mathematics, P. M. T. College, Usilampatti, India
- 2 Department of Mathematics, J. J. College of Arts and Science, Pudukkottai, India
- 3 Department of Mathematics, Sethu Institute of Technology, Kariapatti, India
Abstract
For the first time a mathematical modelling of porous catalyst particles subject to both internal mass concentration gradients as well as temperature gradients, in endothermic or exothermic reactions has been reported. This model contains a non-linear mass balance equation which is related to rate expression. This paper presents an approximate analytical method (Modified Adomian decomposition method) to solve the non-linear differential equations for chemical kinetics with diffusion effects. A simple and closed form of expressions pertaining to substrate concentration and utilization factor is presented for all value of diffusion parameters. These analytical results are compared with numerical results and found to be in good agreement.
- Kierzenka, J. and Shampine, L.F. (2001) A BVP Solver Based on Residual Control and the MATLAB PSE. ACM Transactions on Mathematical Software, 27, 299-316.
- Damkohler, G. (1943) Ubertemperatur in kontaktkornern (Excess Temperature in Catalyst Grains). Zeitschrift f¨ur Physikalische Chemie, 193, 16-28.
- Kim, D.N. and Kim, Y.G. (1981) An Experimental Study of Multiple Steady States in a Porouscatalyst Due to Phase Transition. Journal of Chemical Engineering of Japan, 14, 311-317. http://dx.doi.org/10.1252/jcej.14.311
- Kim, D.H. and Kim, Y.G. (1981) Simulation of Multiple Steady States in a Porous Catalyst Due to Phase Transition. Journal of Chemical Engineering of Japan, 14, 318-322. http://dx.doi.org/10.1252/jcej.14.318
- Jaguste, D.N. and Bhatia, S.K. (1991) Partial Internal Wetting of Catalyst Particles: Hysteresis Effects. AIChE Journal, 37, 650-660. http://dx.doi.org/10.1002/aic.690370503
- Makinde, O.D. (2004) Exothermic Explosions in a Slab: A Case Study of Series Summation Technique. International Communications in Heat and Mass Transfer, 31, 1227-1231. http://dx.doi.org/10.1016/j.icheatmasstransfer.2004.08.020
- Makinde, O.D. (2005) Strong Exothermic Explosions in a Cylindrical Pipe: A Case Study of Series Summation Technique. Mechanics Research Communications, 32, 191-195. http://dx.doi.org/10.1016/j.mechrescom.2004.02.008
- Landau, L.D. and Lifshits, Y.M. (1964) Statistical Physics. Nauka, Moscow. (In Russian)
- Weisz, P.B. and Prater, C.D. (1954) Advances in Catalysis. Academic Press, New York, Vol. 6, p. 143.
- Wicke, E. and Br?tz, W. (1949), Diffusion, Str?mung und Reaktionsgeschwindigkeit im Innern por?ser Kontaktk?rper. Chemie Ingenieur Technik, 21, 219-226. http://dx.doi.org/10.1002/cite.330211104
- Aris, R. (1957) On Shape Factors for Irregular Particles-1: The Steady State Problem, Diffusion and Reaction. Chemical Engineering Sciences, 6, 262-268. http://dx.doi.org/10.1016/0009-2509(57)85028-3
- Weisz, P.B. and Goodwin, R.B. (1963) Combustion of Carbonaceous Deposits within Porous Catalyst Particles I, Diffusion-Controlled Kinetics. Journal of Catalyst, 2, 397-404. http://dx.doi.org/10.1016/0021-9517(63)90104-0
- Weisz, P.B. and Hicks, J.S. (1962) The Behaviour of Porous Catalyst Particles in View of Internal Mass and heat Diffusion Effects. Chemical Engineering Science, 17, 265-275. http://dx.doi.org/10.1016/0009-2509(62)85005-2