As an outcome of globalization and liberalization of economic policies, exploration for and mining of minerals have become one of the recent lucrative trades in India . Due to stringent environment legislations, reclamation and reforestation of the mined out sites have become obligatory. Information on distribution of nutrients before and after mining provide s valuable insights while developing and executing the strategy for reclamation and revegetation of the mined out sites. Successful mine reclamation plan chiefly requires information on the soil characteristics in the area during its natural state. With this aim, investigations into spatial and temporal variations in soil nutrients and other physico - chemical parameters among three proposed bauxite mine locations near Araku valley, India were conducted. Soil samples were collected every three months for two years. At each location, samples from three sites in triplicates from four successive layers (0 - 5 cm , 5 - 10 cm , 10 - 15 cm and 15 - 20 cm depth) were collected. Concentrations of Total Organic Carbon (TOC), Total Nitrogen (TN), Total Available Phosphorous (TAP), Total Available Sulphur (TAS), C:N, C:P, and C:S decreased along the soil layers, while N:P increased. All the parameters studied varied significantly among months (GLM-ANOVA, P < 0.05). Principal Component Analysis (PCA) done on the soil physico-chemical dataset showed first 5 components (Eigen Value > 1) explaining 87.3% of the total variance. Of these, the first component accounted for 21.0% and the second for 20.1% of the total variance. The principal components represented C:N/Soil N, C:P/Soil P/N:P, EC, Soil S/C:S and Soil C axes, respectively.
P. A. Agbu and K. R. Olson, “Spatial Variability of Soil Properties in Selected Illinois Mollisols,” Soil Science Vol. 150, No. 5, 1990, pp. 777-786. doi:10.1097/00010694-199011000-00004
G. Matschonat and R. Vogt, “Effects of Changes in pH, Ionic Strength, and Sulphate Concentration on the CEC of the Temperate Acid Forest,” European Journal of Soil Science, Vol. 48, No. 1, 1997, pp. 163-171. doi:10.1111/j.1365-2389.1997.tb00195.x
K. Kumar, K. V. P. Rao and L. J. Singh, “Forms of Acidity in some Inceptisols under Different Land Use in Manipur,” Journal of the Indian Society of Soil Science, Vol. 43, No. 3, 1995, pp. 338-342.
K. Paliwal and M. Sundaravalli, “Effect of Fire on Nutrient Dynamics in a Semi-Arid Grazing Land Ecosystem of Madurai,” Current Science, Vol. 83, No. 3, 2002, pp. 316- 318.
M. H. Johnston, “Soil-Vegetation Relationships in a Tabonuco Forest Community in the Luquillo Mountains of Puerto Rico,” Journal of Tropical Ecology, Vol. 8, No. 3, 1992, pp. 253-263. doi:10.1017/S0266467400006477
W. L. Silver, F. N. Scatena, A. H. Johnston, T. G. Siccama and M. J. Sanchez, “Nutrient Availability in a Montane Wet Tropical Forest: Spatial Patterns and Methodological Considerations,” Plant Soil, Vol. 164, No. 1, 1994, pp. 129-145. doi:10.1007/BF00010118
M. R. Willig, D. L. Moorhead, S. B. Cox and J. C. Zak, “Functional Diversity of Soil Bacterial Communities in the Tabonuco Forest: The Interaction of Anthropogenic and Natural Disturbance,” Biotropica, Vol. 28, No. 4, 1996, pp. 471-483. doi:10.2307/2389089
B. A. K. Prusty, R. Chandra and P. A. Azeez, “Distribution of Carbon, Nitrogen, Phosphorus, and Sulphur in the Soil in a Multiple Habitat System in India,” Australian Journal of Soil Research, Vol. 47, No. 2, 2009, pp. 177- 189. doi:10.1071/SR08087
F. T. Maestre and J. Cortina, “Spatial Patterns of Surface Soil Properties and Vegetation in a Mediterranean SemiArid Steppe,” Plant Soil, Vol. 241, No. 2, 2002, pp. 279- 291. doi:10.1023/A:1016172308462
D. Robinson, A. Hodge, B. S. Griffiths and A. H. Fitter, “Plant Root Proliferation in Nitrogen-Rich Patches Confers Competitive Advantage,” Proceedings of the Royal Society of London. Series B. Biological Sciences, Vol. 266, No. 1418, 1999, pp. 431–435. doi:10.1098/rspb.1999.0656
J. C. Sharma and Y. Sharma, “Effect of Forest Ecosystems on Soil Properties—A Review,” Agricultural Review, Vol. 25, No. 1, 2004, pp. 16-28.
K. C. Gupta, N. K. Srivastava and R. S. Singh, “Effect of Leaf Litter on Plant Growth Behaviour of Four Species Raised on Mine Spoil,” Indian Journal of Forestry, Vol. 28, No. 4, 2005, pp. 353-358.
B. Majumdar, M. S. Venkatesh and K. Kumar, “Forms of Phosphorous and Soil Acidity in Different Land Management Systems of Meghalaya,” Indian Journal of Forestry, Vol. 30, No. 2, 2007, pp. 127-134.
R. Chandra and P. A. Azeez, “Bioaccumulation of Metals in Different Parts of Weed Species at Proposed Bauxite Mine,” Advance Material Research, Vol. 71-73, 2009, pp. 609-612. doi:10.4028/www.scientific.net/AMR.71-73.609
G. V. SubbaRao and G. R. Kumari, “Flora of Visakhapatnam District Andhra Pradesh,” Botanical Survey of India, Kolkata, 2002.
R. Chandra, B. A. K. Prusty, D. Mythily, S. R. Sarimol and P. A. Azeez, “Nutrients and Alkali Metal Distribution in the Top Soil of Bauxite Rich Hillocks in Araku Valley, Andhra Pradesh, India,” Environmental Science: An Indian Journal, Vol. 2, No. 3, 2007, pp. 145-153.
P. A. Azeez, S. Bhupathy, R. Chandra and T. Selvakumar, “Study of Habitat and Development of Environment Management Plan for Blewitti’s Owl in Araku, Andhra Pradesh,” Andhra Pradesh Mineral Development Corporation (APMDC) Limited, Hyderabad, India by Sálim Ali Centre for Ornithology and Natural History, Coimbatore, 2008.
GEL, “Rapid Environmental Impact Assessment and Environmental Management Plan, Raktakonda Bauxite Deposit, Anantagiri/Paderu RF, Visakhapatnam District, Andhra Pradesh,” Andhra Pradesh Mineral Development Corporation Limited, Secundrabad, India by Geo Experimental Labs, Secundrabad, 2005.
GEL, “Andhra Pradesh Mineral Development Corporation Limited; Rapid Environmental Impact Assessment and Environmental Management Plan, Galikonda Bauxite Deposit, Anantagiri Mandal, Visakhapatnam District, Andhra Pradesh,” Andhra Pradesh Mineral Development Corporation Limited, Secundrabad, India by Geo Experimental Labs, Secundrabad, 2005.
GEL, “Andhra Pradesh Mineral Development Corporation Limited; Rapid Environmental Impact Assessment and Environmental Management Plan, Chittamgondi Bauxite Deposit, Chittamgondi Village, Visakhapatnam District, Andhra Pradesh,” Andhra Pradesh Mineral Development Corporation Limited, Secundrabad, India by Geo Experimental Labs, Secundrabad, 2005.
ICFRE, “Environmental Impact Assessment with Detailed Ecological and Socio-Economic Studies. Proposed Rakthakonda Bauxite Mines Vishakhapatnam,” Andhra Pradesh Mineral Development Corporation Limited by Indian Council of Forestry Research and Education (ICFRE), Dehradun, 2007.
M. L. Jackson, “Soil Chemical Analysis,” Constable & Co Ltd, London, 1958.
H. L. S. Tandon, “Methods of Analysis of Soils, Plants, Waters and Fertilizers,” Fertilizer Development and Consultation Organization, New Delhi, 2001.
D. P. H. Laxen and R. M. Harrison, “Cleaning Methods for Polythene Containers Prior to the Determination of Trace Metals in Fresh Water Samples,” Analytical Chemistry, Vol. 53, No. 2, 1981, pp. 345-350. doi:10.1021/ac00225a051
S. E. Allen, “Chemical Analysis of Ecological Materials,” Blackwell Scientific Publications, London, 1989.
A. Walkey and I. A. Black, “An Examination of the Degljareff Method for Determining the Soil Organic Matter and a Proposed Modification of the Chromic Acid Titration Method,” Soil Science, Vol. 37, No. 1, 1934, pp. 29-38. doi:10.1097/00010694-193401000-00003
A. Raveh and Y. Avnimelech, “Total Nitrogen Analysis in Water, Soil and Plant Material with Persulphate Oxidation,” Plant Research, Vol. 13, No. 9, 1979, pp. 911-912.
A. Kaplan, “The Determination of Urea, Ammonia and Urease,” In: D. Glick, Ed., Methods of Biochemical Analysis, John Wiley and Sons, New York, 1965, pp. 311- 321.
R. H. Bray and L. T. Kurtz, “Determination of Total Organic and Available Forms of Phosphorus,” Soil Science, Vol. 59, No. 1, 1945, pp. 39-46. doi:10.1097/00010694-194501000-00006
A. SubbaRao and K. SammiReddy, “Analysis of Soils for pH, EC and Available Major Nutrients,” In: H. L. S. Tandon, Ed., Methods of Analysis of Soils, Plants, Waters and Fertilizers, Fertilizer Development and Consultation Organization, New Delhi, 2005, pp. 21-59.
M. J. Noru?is, “SPSS/PC+ 4.0 Base Manual—Statistical Data Analysis,” SPSS Inc., Chicago, 1990.
J. B. Orris, “MEGASTAT, Version 8.8,” 2000. http://www.mhhe.com/bstat
C. H. Ettema and G. W. Yeates, “Nested Spatial Biodiversity Patterns of Nematode Genera in a New Zealand Forest and Pasture Soil,” Soil Biology and Biochemistry, Vol. 35, No. 1, 2003, pp. 339-342. doi:10.1016/S0038-0717(02)00276-6
S. N. Yankelevich, C. Fragoso, A. C. Newton, G. Russell and O. W. Heal, “Spatial Patchiness of Litter, Nutrients and Macro Invertebrates during Secondary Succession in a Tropical Montane Forest in Mexico,” Plant Soil, Vol. 286, No. 1-2, 2006, pp. 123-139. doi:10.1007/s11104-006-9031-5
J. Fitcher, M. Turpault, E. Dambrine and J. Ranger, “Localization of Base Cations in Particle Size Fractions of Acid Forest Soils (Vosges mountains, N-E France),” Geoderma, Vol. 82, No. 4, 1998, pp. 295-314. doi:10.1016/S0016-7061(97)00106-7
R. L. Hausenbuiller, “Soil Science Principles and Practices,” WMC brown company publishers, IOWA, Washington, 1978.
W. R. Miller and R. L. Donahue, “Soils in Our Environment,” Prentice-Hall of India Private Limited, New Delhi, 1997.
R. L. Barbosa and P. M. Fearnside, “Carbon and Nutrient Flows in the Amazonian Forest: Fine Litter Production and Composition at Apiau, Roraima, Brazil,” Tropical Ecology, Vol. 37, No. 1, 1996, pp. 115-125.
N. C. Brady, “The Nature and Properties of Soils,” Pentice Hall, Upper Saddle River, 1996.
F. Hagedorn, S. Maurer, P. Egli, P. Blaser, J. B. Bucher and R. Siegwolf, “Carbon Sequestration in Forest Soils: Effect of Soil Type, Atmospheric CO2 Enrichment and N Deposition,” European Journal of Soil Science, Vol. 52, No. 4, 2001, pp. 619-628. doi:10.1046/j.1365-2389.2001.00412.x
R. L. Hendrick and K. S. Pregitzer, “Temporal and Depth-Related Patterns of Fine Root Dynamics in Northern Hardwood Forest,” Journal of Ecology, Vol. 84, No. 2, 1996, pp. 167-176.
B. A. K. Prusty, “Role of Detritus in Trace Metal Dynamics of a Wetland System: A Case Study of Keoladeo National Park, Bharatpur, India,” Report submitted to Council of Scientific and Industrial Research (CSIR), New Delhi, 2008.
J. T. Kao, J. E. Titus and W. X. Zhu, “Differential Nitrogen and Phosphorus Retention by Five Wetland Plant Species,” Wetlands, Vol. 23, No. 4, 2003, pp. 979-987. doi:10.1672/0277-5212(2003)023[0979:DNAPRB]2.0.CO;2
A. Maharudrappa, C. A. Srinivasamurthy, M. S. Nagaraja, R. Siddaramappa and H. S. Anand, “Decomposition Rates of Litter and Nutrient Release Pattern in a Tropical Soil,” Journal of the Indian Society of Soil Science, Vol. 48, No. 1, 2000, pp. 92-97.
B. A. K. Prusty, “Distribution of Select Nutrients and Metals in the Soils of a Wetland-Terrestrial Ecosystem Complex: a case study of Keoladeo National Park, Bharatpur, India,” Ph.D. Dissertation, Bharathiar University, Coimbatore, 2007.
S. C. Chang and M. L. Jackson, “Soil Phosphorous Fraction in Some Representative Soils,” Journal of Soil Science, Vol. 9, No. 1, 1958, pp. 109-119. doi:10.1111/j.1365-2389.1958.tb01903.x
P. S. Ramakrishnan and O. P. Toky, “Soil Nutrient Status of Hill Agro-Ecosystems and Recovery Pattern after Slash and Burn Agriculture (Jhum) in North-Eastern India,” Plant Soil, Vol. 60, No. 1, 1981, pp. 41-64. doi:10.1007/BF02377111
S. Venkatachalam, Kalaiselvi, K. S. Neelakantan and S. Gunasekaran, “A Comparative Study on Soil Microflora and Nutrient Status of Sholas and Adjoining Vegetation,” Indian Journal of Forestry, Vol. 30, No. 2, 2007, pp. 135- 140.
A. P. Aluko, “Soil Properties and Nutrient Distribution in Terminalia superba Stands of Different Age Series Grown in Two Soil Types of Southwestern Nigeria,” Forest Ecology and Management, Vol. 58, No. 1-2, 1993, pp. 153-161. doi:10.1016/0378-1127(93)90137-C
A. Arunachalam and K. Arunachalam, “Community Characteristics and Soil Biological Processes during Regrowth of Subtropical Forest Ecosystems,” Indian Journal of Forestry, Vol. 28, No. 1, 2005, pp. 5-10.
M. Hossain and S. Othman, “Degradation Rate of Leaf Litter of Bruguiera parviflora of Mangrove Forest of Kuala Selangor, Malaysia,” Indian Journal of Forestry, Vol. 28, No. 2, 2005, pp. 144-149.
A. Vairavamurthy and S. Wang, “Organic Nitrogen in Geomacromolecules: Insights of Speciation and Transformation with K-Edge XANES Spectroscopy,” Environment, Science and Technology, Vol. 36, No. 14, 2002, pp. 3050-3056. doi:10.1021/es0155478
R. Srivastava and K. P. Singh, “Variations in Soil Organic Carbon and Storage due to Cultivation Practices in the Gangetic Plain, India,” International Journal of Ecology and Environmental Sciences, Vol. 28, 2002, pp. 193- 199.
H. Vejre, I. Callesen, L. Vesterdal and K. Raulund-Rasmussen, “Carbon and Nitrogen in Danish Forest SoilsContents and Distributions Determined by Soil Order,” Soil Science Society of American Journal, Vol. 67, No. 1, 2003, pp. 335-343. doi:10.2136/sssaj2003.0335
B. A. K. Prusty, R. Chandra and P. A. Azeez, “Macronutrients along the Sediment Core in a Subtropical Monsoonal Wetland in India,” Wetland Ecology and Management, Vol. 18, No. 1, 2010, pp. 91-105. doi:10.1007/s11273-009-9151-9