Atomic Absorption and Vibrational Spectral Magnetic Studies on the Removal of Cu(II) and Co(II) Ions Using Synthetic Nano Adsorbent Fe<sub>3</sub>O<sub>4</sub>
- 1 Department of Chemistry, Kalasalingam University, Krishnankoil, India;
- 2 Department of Chemistry, Kalasalingam University, Krishnankoil, India;
- 3 Department of Physics, Thiagarajar College of Engineering, Madurai, India;
- 4 Department of Physics, Thiagarajar College of Engineering, Madurai, India
- 5 Department of Chemistry, Thiagarajar College of Engineering, Madurai, India.
Abstract
Adsorption of Cu(II) and Co(II) from aqueous solutions on synthetic nano Fe 3 O 4 has been studied. The effect of experimental parameters such as initial concentration of the metal ions, adsorbent dosage, contact time and pH has been investigated. Optimum removal efficiency of Cu(II) ion was found to be 97.8% with the dose rate of 1.07 g/L in 60 minutes at pH = 5.5 and for Co(II) ion, it was found to be 99.2% with the dose rate of2.57 g/L in 10 minutes at pH = 5.4. The removal of Co(II) ions require only 10 minutes with the efficient removal of 99.2%, whereas Cu(II) ions require 60 minutes with the maximum removal of 97.8%. In order to understand the effective removal of Cu(II) and Co(II) ions on Fe 3 O 4 , room temperature magnetic measurement w as carried out using Vibrational Spectrum Magnetometer (VSM), before and after adsorption with a maximum applied magnetic field of 20 , 000 G .
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