Physical Properties in Aqueous Solutions for a Series of Alkyltrimethylammonium Salicylates (C12TA-Sal through C16TA-Sal): From a View Point of Drag Reduction
Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
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Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
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Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
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Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
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Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
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Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
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Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
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Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
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Chukyo Yushi Co. Ltd., Nagoya, Japan
1 Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
2 Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
3 Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
4 Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
5 Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
6 Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
7 Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
8 Graduate School of Engineering, Nagoya Institute of Technology, Nagoya, Japan
Compounds for a series of alkyltrimethylammonium salicylates (C12TA-Sal through C16TA-Sal) were synthesized. Their physical properties in aqueous solutions were investigated by conductometry, viscometry, vortex inhibition, viscoelastic recoil and swirling decay time from a view point of drag reduction. For critical micelle concentrations (CMC) obtained for a series of compounds by conductometry, it was found that a linear relation of the form, log(CMC)= 4.088 ﹣ 0.305*Nc (Nc: carbon number in the alkyl chain), holds. From the viscosity measurement, all the compounds showed viscosity increase above their CMC. Vortex inhibition was observed above the CMC for the compounds with the chain length longer than C13. Viscoelastic recoil was observed above the concentration of one and a half times the CMC for the compounds with alkyl chain length longer than C14.
Bewersdorf, H.-W. and Ohlendorf, D. (1988) The Behaviour of Drag-Reducing Cationic Surfactant Solutions. Colloid and Polymer Science, 266, 941-953. https://doi.org/10.1007/BF01410851
Gyr, A. and Bewerddorff, H.-W. (1995) Drag Reduction of Turbulent Flows by Additives. Kluwer Academic Publishers, Dordrecht/Boston/London. http://link.springer.com/book/10.1007%2F978-94-017-1295-8
Hellsten, M. (2002) Drag-Reducing Surfactants. Journal of Surfactants and Detergents, 5, 65-70.
Saeki, T., Tokuhara, K. and Matsumuta, T. (2008) Development and Spread of Energy Saving Technology by Using Drag-reducing Additives. The Eighth Green and Sustainable Chemistry Award Awarded by the Minister of the Environment in Japan. http://www.jaci.or.jp/english/gscn/awards/aw20090902_01.html
Kishimoto, A., Nishimura, K. and Kashiwagi, A. (2007) Drag Reduction Additive for Centralized Air-Conditioning of Buildings. The SCEJ Technical Achievement Award in 2007 Awarded by Society of Chemical Engineering, Japan. http://www.scej.org/en/awards/scej-award/scej-award-for-otd.html
Gordon, R.J. and Balakrishnan, A. (1972) Vortex Inhibition: A New Viscoelastic Effect with Importance in Drag Reduction and Polymer Characterization. Journal of Applied Polymer Science, 16, 1629-1639. http://onlinelibrary.wiley.com/doi/10.1002/app.1972.070160704/abstract
Harwigsson, I. and Hellsten, M. (1996) Environmentally Acceptable Drag-Reducing Surfactants for District Heating and Cooling. Journal of the American Oil Chemists’ Society, 73, 921-928. https://doi.org/10.1007/BF02517996
Zakin, J.L., Kawaguchi, Y., Talmon, Y. and Hart, D.J. (2006) Development of Practical Drag Reduction System for District Cooling Systems. NEDO Report, Registration Number: 2002EF001. http://www.nedo.go.jp/content/100084667.pdf#search='NEDO+Report%2C+Registration+Number%3A+2002EF001
Gravsholt, S. (1976) Viscoelasticity in Highly Dilute Aqueous Solutions of Pure Cationic Detergents. Journal of Colloid and Interface Science, 57, 575-577. https://doi.org/10.1016/0021-9797(76)90236-8
Hyde, A.J. and Stevenson, D.M. (1969) The Effect of Organic Additives on Paraffin Chain Electrolyte Solutions. Part IV. Electrical Conductance Measurements on Solubilised Solutions of Hydrocarbons. Kolloid-Zeitschrift und Zeitschrift für Polymere, 232, 797-804. https://doi.org/10.1007/BF01500658
Physical Properties in Aqueous Solutions for a Series of Alkyltrimethylammonium Salicylates (C12TA-Sal through C16TA-Sal): From a View Point of Drag Reduction — Oak Academic Publishing
Rao, U.R.K., Manohar, C., Valailokar, B.S. and Iyer, R.M. (1987) Micellar Chain Model for the Origin of the Visoelasticity in Dilute Surfactant Solutions. The Journal of Physical Chemistry, 91, 3286-3291. https://doi.org/10.1021/j100296a036
Kato, M., Takahashi, T. and Shirakashi, M. (2006) Influence of Planar Elongation Strain on Flow-Induced Structure and Flow Instability of CTAB/Nasal Aqueous Solution. Nippon Kikai Gakkai Ronbunshu, B-hen, 72, 1935-1942. https://www.jstage.jst.go.jp/article/kikaib1979/72/720/72_720_1935/_pdf
Bogue, D.C. and Doughty, J.O. (1966) Comparison of Constitutive Equations for Viscoelastic Fluids. Industrial & Engineering Chemistry Fundamentals, 5, 243-252.
Itoh, M., Tamano, S., Yokota, K. and Ninagawa, M. (2005) Velocity Measurement in Turbulent Boundary Layer of Drag-Reducing Surfactant Solution. Physics of Fluids, 17, Article ID: 075107. https://doi.org/10.1063/1.1979523
Johansson, L., Lindblom, G., Gravsholt, S. and Norden, B. (1979) Viscoelastic Amphiphile Aqueous Solutions Studied by Linear Dichroism Spectroscopy. Journal of Colloid and Interface Science, 69, 358-361. https://doi.org/10.1016/0021-9797(79)90170-X
Gravsholt, S. (1979) Rheopectic Behavior of Highly Dilute Viscoelastic Aqueous Detergent Solutions. Naturwissenschaften, 66, 263-264. https://doi.org/10.1007/BF00571610
Angel, M., Hoffmann, H., Lobl, M., Reizlein, K., Thurn, H. and Wunderlich, I. (1984) From rodlike micelles to lyotropic liquid crystals. Progress in Colloid and Polymer Science, 69, 12-28.
Imae, T., Hashimoto, K. and Ikeda, S. (1990) The Spinnability of Viscoelastic Solutions of Tetradecyl- and Hexadecyl-Trimethylammonium Salicylates. Colloid and Polymer Science, 268, 460-468. https://doi.org/10.1007/BF01411005
Imae, T. (1990) Light Scattering of Spinnable, Viscoelastic Solutions of Hexadecyltrimethylammonium Salicylate. Journal of Physical Chemistry, 94, 5953-5959. https://doi.org/10.1021/j100378a063
Imae, T. and Kohsaka, T. (1992) Size and Electrophoretic Mobility of Tetradecyltrimethylammonium Salicylate (C14TASal) Micelles in Aqueous Media. Journal of Physical Chemistry, 96, 10030-10035. https://doi.org/10.1021/j100203a081
Hashimoto, K., Imae, T. and Nakazawa, K. (1992) The Viscoelasticity of Spinnable Solutions of Alkyltrimethylammonium Salicylates. Colloid and Polymer Science, 270, 249-258. https://doi.org/10.1007/BF00655477
Imae, T., Kato, M. and Rutland, M. (2000) Forces between Two Glass Surfaces with Adsorbed Hexadecyltrimethylammonium Salicylate. Langmuir, 16, 1937-1942. https://doi.org/10.1021/la990824y
Alfaro, J., Landázuri, G., González-álvarez, A., Macías, E.R., Fernandez, V., Shulz, P., Rodríguez, J. and Soltero, J. (2010) Phase and Rheological Behavior of the Hexadecyl(Trimethyl)Azanium, 2-Hydroxybenzoate/Water System. Journal of Colloid and Interface Science, 351, 171-179. https://doi.org/10.1016/j.jcis.2010.07.038
Birdi, K.S. (1986) Determination of C.M.C. and Aggregation Numbers for Some Cationic Surfactants. Acta Chemica Scandinavica, 40A, 319-321. https://doi.org/10.3891/acta.chem.scand.40a-0319
Mukerjee, P. and Mysels, K.J. (1971) Critical Micellar Concentration of Aqueous Surfactant Systems. National Bureau of Standard, Washington.
Basu Ray, G., Charkraborty, I., Ghosh, S., Moulik, S.P. and Palepu, R. (2005) Self-Aggregation of Alkyltrimethylammonium Bromides (C10-, C12-, C14-, and C16TAB) and Their Binary Mixtures in Aqueous Medium: A Critical and Comprehensive Assessment of Interfacial Behavior and Bulk Properties with Reference to Two Types of Micelle Formation. Langmuir, 21, 10958-10967. https://doi.org/10.1021/la051509g
Ribeiro, A.C.F., Lobo, V., Valente, A., Azvedo, E., Miguel, M. and Burrows, H. (2004) Transport Properties of Alkyltrimethylammonium Bromide Surfactants in Aqueous Solutions. Colloid and Polymer Science, 283, 277-283. https://doi.org/10.1007/s00396-004-1136-x
Carpena, P., Aguiar, J., Bernaola-Galván, P. and Carnero Ruiz, C. (2002) Problems Associated with the Treatment of Conductivity-Concentration Data in Surfactant Solutions: Simulations and Experiments. Langmuir, 18, 6054-6058. https://doi.org/10.1021/la025770y
Moulik, S.P., Haque, M.E., Jana, P.K. and Das, A.R. (1996) Micellar Properties of Cationic Surfactants in Pure and Mixed States. Journal of Physical Chemistry, 100, 701-708. https://doi.org/10.1021/jp9506494
Garcfa-Mateos, I., Velázques, M.M. and Rodriguez, L. (1990) Critical Micelle Concentration Determination in Binary Mixtures of Ionic Surfactants by Deconvolution of Conductivity/Concentration Curves. Langmuir, 6, 1078-1083. https://doi.org/10.1021/la00096a009
Evans, D.F., Allen, M., Ninham, B.W. and Fouda, A. (1984) Critical Micelle Concentrations for Alkyltrimethylammonium Bromides in Water from 25 to 160°C. Journal of Solution Chemistry, 13, 87-101. https://doi.org/10.1007/BF00646042
Rodriguez, A., Junquera, E., del Burgo, P. and Aicart, E. (2004) Conductometric and Spectrofluorimetric Characterization of the Mixed Micelles Constituted by Dodecyltrimethylammonium Bromide and A Tricyclic Antidepressant Drug in Aqueous Solution. Journal of Colloid and Interface Science, 269, 476-483. https://doi.org/10.1016/j.jcis.2003.09.028
Czapkiewicz, J., Dlugolecka, M. and Bozena, T. (2004) 10-Methylacridinium Ion as a Fluorimetric Probe Measuring the Activity of Halide Anions in Aqueous Solutions of Cationic Surfactants. Journal of Colloid and Interface Science, 276, 227-230. https://doi.org/10.1016/j.jcis.2004.03.020
Evans, D.F. and Wightman, P.J. (1984) Micelle Formation above 100°C. Journal of Colloid and Interface Science, 86, 515-524. https://doi.org/10.1016/0021-9797(82)90096-0
Charkraborty, T., Ghosh, S. and Moulik, S.P. (2005) Micellization and Related Behavior of Binary and Ternary Surfactant Mixtures in Aqueous Medium: Cetyl Pyridinium Chloride (CPC), Cetyl Trimethyl Ammonium Bromide (CTAB), and Polyoxyethylene (10) Cetyl Ether (Brij-56) Derived System. Journal of Physical Chemistry B, 109, 14813-14823. https://doi.org/10.1021/jp044580o
Klevens, H.B. (1953) Structure and Aggregation in Dilute Solution of Surface Active Agents. Journal of the American Oil Chemists’ Society, 30, 74-80. https://doi.org/10.1007/BF02635002
Ohlendorf, D., Interhat, W. and Hoffmann, H. (1986) Surfactant Systems for Drag Reduction: Physico-Chemical Properties and Rheological Behaviour. Rheologica Acta, 25, 468-486. https://doi.org/10.1007/BF01774397