Mechanical, Thermal and Chemical Durability Behaviors of CdO-Bi<sub>2</sub>O<sub>3</sub> Boro-Phosphate Glasses Containing Fe<sub>2</sub>O<sub>3</sub>
- 1 Department of Physics, Faculty of Science, Al-Azhar University, Women Branch, Nasr City, Cairo, Egypt
- 2 Department of Physics, Faculty of Science, Al-Azhar University, Women Branch, Nasr City, Cairo, Egypt
- 3 Department of Physics, Faculty of Science, Ain Shams University, Cairo, Egypt
- 4 Department of Physics, Faculty of Science, Al-Azhar University, Women Branch, Nasr City, Cairo, Egypt
- 5 Department of Physics, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt
- 6 Department of Physics, Faculty of Science, Al-Azhar University, Women Branch, Nasr City, Cairo, Egypt
Abstract
The glass system x Bi 2 O 3 - (30 – x )CdO-10B 2 O 3 - 20Fe 2 O 3 - 40P 2 O 5 (0 ≤ x ≤ 30 weight %), has been prepared by the melt quenching technique. The thermal stability of the glasses, their hardness as well as their chemical durability have been investigated before and after subjecting to different gamma ray doses to insure the validity of this glass system for ap plication to the problem of the permanent disposal for nuclear wastes. The results indicated that the glasses have well to excellent chemical durability, thermal stability and hardness with increasing Bi 2 O 3 content on the expense of CdO, and that the effect of irradiation with gamma doses is very small.
- A. J. Connelly, R. J. Hand, P. A. Bingham and N. C. Hyatt, “Mechanical Properties of Nuclear Waste Glasses,” Journal of Nuclear Materials, Vol. 408, No. 2, 2011, pp. 188-193. doi:10.1016/j.jnucmat.2010.11.034
- P. A. Bingham, N. C. Hyatt, R. J. Hand, C. R. Wilding, “Effects of Modifier Additions on the Thermal Properties, Chemical Durability, Oxidation State and Structure of Iron Phosphate Glasses,” Journal of Non-Crystalline Solids, Vol. 355, No. 28-30, 2009, pp. 1526-1538. doi:10.1016/j.jnoncrysol.2009.03.008
- P. A. Bingham and R. J. Hand, “Vitrified Metal Finishing Wastes: II. Thermal and Structural Characterisation,” Journal of Hazardous Materials, Vol. 119, No. 1-3, 2005, pp. 125-133. doi:10.1016/j.jhazmat.2005.03.031
- M. Karabulut, B. Yuce, O. Bozdogan, H. Ertap and G. M. Mammadov, “Effect of Boron Addition on the Structure and Properties of Iron Phosphate Glasses,” Journal of Non-Crystalline Solids, Vol. 357, No. 5, 2011, pp. 14551462. doi:10.1016/j.jnoncrysol.2010.11.023
- P. A. Bingham, R. J. Hand and S. D. Forder, “Preliminary Studies of Sulphate Solubility and Redox in 60P2O540Fe2O3 Glasses,” Materials Letters, Vol. 60, No. 6, 2006, pp. 844-847. doi:10.1016/j.matlet.2005.10.029
- H. E. Davies, G. E. Troxell and C.T. Wiskocil, “The Testing and Inspection of Engineering Materials,” 3rd Edition, McGraw-Hill, New York, 1994.
- H. A. Saudi, A. G. Mostafa, N. Sheta, S. U. El Kameesy and H. A. Sallam, “The Structural Properties of CdOBi2O3 Borophosphate Glass System Containing Fe2O3 and Its Role in Attenuating Neutrons and Gamma Rays,” Physica B: Condensed Matter, Vol. 406, No. 21, 2011, pp. 4001-4006. doi:10.1016/j.physb.2011.06.038
- K. K. Rao and D. B. Sirdeshmukh, “Microhardness and Interatomic Binding in Some Cubic Crystals,” Bulletin of Materials Science, Vol. 5, No. 5, 1983, pp. 449-452. doi:10.1007/BF02743923
- C. R. Kurkjian, “Mechanical Properties of Phosphate Glasses,” Journal of Non-Crystalline Solids, Vol. 263-264, 2000, pp. 207-212. doi:10.1016/S0022-3093(99)00637-7
- H. A. El-Batal, F. A. Khalifa and M. A. Azooz, “Absorption and Infrared Spectra of Gamma Irradiated Ternary Silicate Glasses Containing Cobalt,” Indian Journal of Pure and Applied Physics, Vol. 42, No. 10, 2001, pp. 711-721.
- M. Karabulut, B. Yuce, O. Bozdogan, H. Ertap and G. M. Mammadov, “Effect of Boron Addition on the Structure and Properties of Iron Phosphate Glasses,” Journal of Non-Crystalline Solids, Vol. 357, No. 5, 2011, pp. 14551462. doi:10.1016/j.jnoncrysol.2010.11.023