The Role of Replacing CdO by Fe<sub>2</sub>O<sub>3</sub> on the Fast Neutron Removal Cross Sections in Cd-Boro Phosphate Glass Shield
- 1 Physics Department, Faculty of Science, Al-Azhar University, Girls Branch, Cairo, Egypt
- 2 Physics Department, Faculty of Science, Al-Azhar University, Girls Branch, Cairo, Egypt
Abstract
This work deals with the application of [MERCSF-N ] computer program in calculating the macroscopic effective re moval cross-section of fast neutrons, Σ R (cm -1 ), for two different boro phosphate glass systems: (0.5 - x) CdO-x Fe 2 O 3 - 0.4 P 2 O 5 -0.1 B 2 O 3 and (0.5 - x) B 2 O 3 -x Fe 2 O 3 -0.1 CdO-0.4 P 2 O 5 (with 0.05 ≤ x ≤ 0.5 by mole), to realize from the role of iron in the attenuation process and hence the usefulness of the glass containing iron as neutrons shielding material. The effect of replacing cadmium and boron oxides by iron oxide has been analyzed which proved that iron is more efficient than cadmium in attenuating and removing fast neutrons and that the presence of small amounts of B 2 O 3 at least 0.1 mole fraction, with iron is needed to aid improving the removal cross-section of iron phosphate glasses. Ex perimental IR results are developed and used to trace the structural change and confirm the role of iron in the removal cross section.
- S. H. Im, Y. H. Na, N. J. Kim, D. H. Kim, C. W. Hwang and B. K. Ryu, “Structure and Properties of Zinc Bismuth Phosphate Glass,” Thin Solid Films, Vol. 518, No. 24, 2010, pp. e46-e49. doi:10.1016/j.tsf.2010.03.128
- J. A. Wilder, “Phosphate Glass Dissolution in Aqueous Solutions,” Journal of Non-Crystalline Solids, Vol. 38-39, 1984, pp. 879-884. doi:10.1016/0022-3093(80)90548-7
- X. Fang, C. S. Ray, A. Mogus-Milankovic and D. E. Day, “Iron Redox Equilibrium, Structure, and Properties of Iron Phosphate Glasses,” Journal of Non-Crystalline Solids, Vol. 283, No. 3, 2001, pp. 162-172. doi:10.1016/S0022-3093(01)00416-1
- P. A. Bingham, R. J. Hand, S. D. Forder and A. Lavaysierre, “Vitrified Metal Finishing Wastes: II. Thermal and Structural Characterisation,” Journal of Hazardous Materials, Vol. 122, No. 1-2, 2005, pp. 129-138. doi:10.1016/j.jhazmat.2005.03.031
- M. H. Kharita, S. Yousef and M. Al Nassar, “Review on the Addition of Boron Compounds to Radiation Shielding Concrete,” Progress in Nuclear Energy, Vol. 53, No. 2, 2011, pp. 207-211. doi:10.1016/j.pnucene.2010.09.012
- H. A. Saudi, A. G. Mostafa, N. Sheta, S. U. El Kameesy and H. A. Sallam, “The Structural Properties of CdOBi2O3 Borophosphate Glass System Containing Fe2O3 and Its Role in Attenuating Neutrons and Gamma Rays,” Physica B: Condensed Matter, Vol. 406, No. 21, 2011, pp. 4001-4006.
- E. P. Blizard and L. S. Abbott, “Introduction to Nuclear Engineering 3rd Ed.,” John Wiley & Sons, Inc., Hoboken, 1962.
- J. Wood, “Computational Methods in Reactor Shielding,” Pergamon Press, Inc., New York, 1982.
- M. F. Kaplan, “Concrete Radiation Shielding: Nuclear Physics, Concrete Properties, Design and Construction,” John Wiley & Sons, New York, 1989.
- Y. Iwamoto and R. M. Ronningen, “Attenuation of Ambient Dose Equivalent from Neutrons by Thick Concrete, Cast Iron and Composite Shields for High Energy Proton, 3He, 48Ca and 238U Ions on Cu Targets for Shielding Design,” Nuclear Instruments and Methods in Physics Research Section B, Vol. 269, No. 3, 2011, pp. 353-363. doi:10.1016/j.nimb.2010.11.046
- H. S. Liu, P. Y. Shih and T. S. Chin, “High Photoluminescent Property of Low-Melting Sn-Doped Phosphate Glass,” Applied Physics Express, Vol. 3, No. 8, 2010, p. 227.
- V. V. Kushnikov, Y. I. Matyunin, T. V. Smelova and A. V. Demin, “Investigations of Plutonium Immobilization into the Vitreous,” Materials Research Society Symposium Proceedings, Vol. 465, 1997, p. 55.