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International Journal of Organic Chemistry (IJOC) is an international, specialized, English-language journal devoted to publication of original contributions concerning all field of organic chemistry. It is an open-access, peer-reviewed journal describing the synthetic approached and the design of new molecules for ap…
Ling Dang, Qiang Li, Tongmei Ma, Sheng Sheng, Wei Zeng
An efficient BF<sub>3</sub>.OEt<sub>2</sub>-promoted benzylation of arenes and heteroarenes with various benzyl ether derivatives has been developed. This method provided alternative access to valuable diarylmethane in good yields under mild conditions via an…
N. Subhakara Reddy, A. Srinivas Rao, M. Adharvana Chari, V. Ravi Kumar, V. Jyothi, V. Himabindu
Synthesis and antibacterial activity of some novel urea and thiourea derivatives (7a-7k, 8a-8f) of anacardic acid prepared from commercially available anacardic acid which is obtained from natural product Cashew Nut Shell Liquid (CNSL). Compounds (7a-7k, 8a-8…
Caiyun Zhao, Li Xu, Jianwu Shi, Chunli Li, Zhihua Wang, Hua Wang
In this paper, the synthetic method for making 7,7’-dimethyl-2,5-bis(trimethylsilyl)-dithieno[2,3-b:3’,2’-d] silole (1) was developed by using 2,2’-dibromo-5,5’-bis-trimethyl-silanyl[3,3’]bithiophenyl as starting material in one pot reaction. In the presence…
Jun-ichi Kadokawa, Hironori Izawa, Tomoya Ohta, Satoshi Wakizono, Kazuya Yamamoto
Reduction of methylene blue (MB) occurred by photo irradiation at 280 - 370 nm wavelengths to a solution of MB in an ionic liquid, 1-butyl-3-methylimidazolium chloride (BMIMCl), which was confirmed by color change and UV-Vis measurement of the solution. Furth…
Somannagari Shylaja, Kola Ramesh, Pochampally Giridhar Reddy, Kamatala Chinna Rajanna, Pondichery Kuppuswamy Saiprakash
Oxidation of Xanthine alkaloid have been studied with various one and two electron oxidizing agents using PEGs and micelle forming surfactants. The reaction is too sluggish in solution phase, but moderately fast in presence of PEGs and micelles. However, the…
Azizollah Habibi, Enayatollah Sheikhhosseini, Mohammadali Bigdeli, Saeed Balalaie, Elinaz Farrokhi
We wish to report a mild and efficient Crossed-Aldol reaction for the synthesis of α, ?-bis(substituted-ben- zylidene)cycloalkanones in the presence of catalytic amounts of covalently anchored sulfonic acid onto sil- ica gel under heterogeneous and solvent-fr…
Garima Tripathi, Deepak Srivastava
The degradation of the epoxy system was studied for the prepared six blend samples with the incorporation of 0 wt% - 25 wt% carboxyl terminated butadiene acrylonitrile (CTBN) copolymer, on a dynamic basis using Thermo gravimetric analysis (TGA) technique unde…
Hamdi M. Hassaneen, Huwaida M. E. Hassaneen, Zakaria Ahmed Gomaa
The coupling reaction of 3-cyanoacetyl-2-methylindole 1a with the aromatic diazonium salts gave the corresponding arylhydrazones <b>2a-e</b>. Compounds <b>2</b> were used for synthesis of 4-aminopyrazole-5-carbonitrile <b>4a-e</b> and 5-amino-4-arylazo-3-pyra…
Theresa I. Edewor, Abass A. Olajire
Two new flavones, namely 5,7,2’,5’-tetrahydroxy-3,4’-dimethoxyflavone and 5’-acetoxy-5,7,2’-trihydroxy-3, 4’-dimethoxyflavone were successfuly isolated from the leaves of <i>Acanthospermum hispidum</i> DC and identified by UV-Vis, IR, <sup>1</sup>H-NMR and EI…
Layla Mhamdi, Hafedh Bohli, Younes Moussaoui, Ridha ben Salem
We describe in this work the influence of the addition of phase transfer catalyst in heterogeneous medium liquid/liquid on the output of the reactions of Darzens and Henry. It proves that the reaction of Darzens is favoured in the presence of low base such as…
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International Journal of Organic Chemistry (IJOC) is an international, specialized, English-language journal devoted to publication of original contributions concerning all field of organic chemistry. It is an open-access, peer-reviewed journal describing the synthetic approached and the design of new molecules for ap… All articles are open access under a CC BY 4.0 licence, with authors retaining copyright.
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